Hydrothermal synthesis of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5[V0.324+V0.685+O2PO4{P(OH)2}0.44]

被引：0
作者：
Ayyappan, P
Asnani, M
Ramanan, A [1 ]
Piffard, Y
机构：
[1] Indian Inst Technol, Dept Chem, New Delhi 110016, India
[2] Univ Nantes, CNRS, Chim Solide Lab, Inst Mat Nantes, Nantes, France
来源：
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES | 2003年 / 115卷 / 01期
关键词：
vanadyl phosphate; hydrothermal synthesis; intercalation; single crystal structure;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper we report the hydrothermal synthesis and characterisation of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)(0.5) [V0.324+V0.685+O2PO4(P(OH)(2)}(0.44)]. The phase purity of the solid was established using powder X-ray diffraction, single crystal X-ray diffraction, TGA, DTA, FTIR, UV-Vis and magnetic susceptibility measurements. Crystal data: orthorhombic, Prima, a=9.0289, b=8.8962 and c=15.9813 Angstrom, V=1283.7Angstrom(3), Z=8. The structure contains layers made of VO5 square pyramids and PO4 tetrahedra; adjacent layers are connected through disordered tetrahedral PO2(OH)(2) units. Ethylenediammonium cations occupy cavities in between the layers.
引用
收藏
页码：33 / 40
页数：8
相关论文
共 50 条
[21]   SYNTHESIS AND CHARACTERIZATION OF ALPO4-12 MOLECULAR-SIEVE FROM H3PO4-I-C3H7OAL-H2NCH2CH2NH2-HOCH2CH2OH SYSTEM [J].
GAO, QM ;
LI, SG ;
XU, RR .
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1995, 16 (03) :338-341
[22]   Synthesis and spectral characterization of a new molybdenum phosphate compound (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)]•7H2O [J].
Li, ZZ ;
Zhang, HH ;
Huang, CC ;
Sun, RQ ;
Zheng, XL .
SPECTROSCOPY AND SPECTRAL ANALYSIS, 2002, 22 (06) :1048-1050
[23]   Preparation and composition-structure-thermal stability relation of a novel open-franiework vanadium phosphate (H3NCH2CH2NH3)3[(VO)4(PO4)2(HPO4)4] [J].
Yang, ZZ ;
Liao, LB ;
Du, HB ;
Xiong, M ;
Ma, ZS .
JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING, 2002, 9 (01) :36-39
[24]   Synthesis and characterization of a novel hybrid single crystal [Ga3(PO4)3F2]H3O • (H3NCH2CH2)2NH2 [J].
Yao, YW ;
Zhao, YN ;
Yue, ST ;
Xu, HL ;
Liang, HB ;
Zhao, DQ .
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2001, 22 (09) :1450-1452
[25]   Hydrothermal synthesis and crystal structure of a new polyoxometalate (CH3CH2)4N]4H3O{ Na[(HMo2O5)3(HPO4) (H2PO4)3]2} • (H2PO4)2 • 10H2O [J].
Zhang, H ;
Xu, L ;
Wang, EB ;
Hu, CW ;
Chen, JT ;
Yao, YG ;
Qin, YY .
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (06) :1010-1012
[26]   Hydrothermal synthesis and characterization of (H3N(CH2)4NH3)[V6O14] [J].
Sediri, F ;
Etteyeb, N ;
Steunou, N ;
Guyard-Duhayon, C ;
Maquet, J ;
Gharbi, N ;
Livage, J .
JOURNAL OF SOLID STATE CHEMISTRY, 2002, 167 (02) :407-411
[27]   Hydrothermal synthesis and structure of a new arsenic-vanadium cluster:: [NH2(CH2CH2)2NH2]3 [As8V14O42(SO4)]•6.5H2O [J].
Zheng, ST ;
Zhang, H ;
Yang, GY .
JOURNAL OF MOLECULAR STRUCTURE, 2004, 705 (1-3) :127-132
[28]   Synthesis, structure and properties of (H2NCH2CH2NH3)3 {(VO)6 [B10O16 (OH)6]2} • 11H2O [J].
Cai, Qinghai ;
Lu, Bin ;
Zhang, Jiawei ;
Shan, Yongkui .
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2008, 38 (05) :321-325
[29]   Synthesis, Structure and Properties of (H2NCH2CH2NH3)3 {(VO)6 [B10O16 (OH)6]2} · 11H2O [J].
Qinghai Cai ;
Bin Lu ;
Jiawei Zhang ;
Yongkui Shan .
Journal of Chemical Crystallography, 2008, 38 :321-325
[30]   Hydrothermal synthesis and characterizaton of [CH3NH3][NH3(CH2)6NH3]H3[P2Mo2W16O62] • H2O [J].
Liu, ZR ;
Wang, L ;
Chen, BG ;
Xu, L ;
Wang, EB ;
Xing, Y ;
Jia, HQ ;
Lin, YH .
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2003, 24 (05) :772-775
12345