Hydrothermal synthesis of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5[V0.324+V0.685+O2PO4{P(OH)2}0.44]

被引：0
|
作者：
Ayyappan, P
Asnani, M
Ramanan, A [1 ]
Piffard, Y
机构：
[1] Indian Inst Technol, Dept Chem, New Delhi 110016, India
[2] Univ Nantes, CNRS, Chim Solide Lab, Inst Mat Nantes, Nantes, France
来源：
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES | 2003年 / 115卷 / 01期
关键词：
vanadyl phosphate; hydrothermal synthesis; intercalation; single crystal structure;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper we report the hydrothermal synthesis and characterisation of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)(0.5) [V0.324+V0.685+O2PO4(P(OH)(2)}(0.44)]. The phase purity of the solid was established using powder X-ray diffraction, single crystal X-ray diffraction, TGA, DTA, FTIR, UV-Vis and magnetic susceptibility measurements. Crystal data: orthorhombic, Prima, a=9.0289, b=8.8962 and c=15.9813 Angstrom, V=1283.7Angstrom(3), Z=8. The structure contains layers made of VO5 square pyramids and PO4 tetrahedra; adjacent layers are connected through disordered tetrahedral PO2(OH)(2) units. Ethylenediammonium cations occupy cavities in between the layers.
引用
收藏
页码：33 / 40
页数：8
相关论文
共 50 条
  • [1] Hydrothermal synthesis of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5[V0.324+V0.685+O2PO4{P(OH)2}0.44]0.44]
    Ayyappan, P.
    Asnani, Minakshi
    Ramanan, A.
    Piffard, Y.
    JOURNAL OF CHEMICAL SCIENCES, 2003, 115 (01) : 33 - 40
  • [2] Hydrothermal synthesis of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5[V0.324+V0.685+O2PO4{P(OH)2}0.44]0.44]
    P. Ayyappan
    Minakshi Asnani
    A. Ramanan
    Y. Piffard
    Proceedings / Indian Academy of Sciences, 2003, 115 : 33 - 40
  • [3] Hydrothermal synthesis and crystal structure of (H3NCH2CH2NH3)[V(OH)(HPO4)2].H2O with novel 1-D {v3+-OH-v3+} polymeric chains
    Zhang, YP
    Warren, CJ
    Clearfield, A
    Haushalter, RC
    POLYHEDRON, 1998, 17 (15) : 2575 - 2580
  • [4] Hydrothermal synthesis and structure characterization of a novel open-framework vanadium phosphate (H3NCH2CH2NH3)3[(VO)4(PO4)2(HPO4)4]
    Du, HB
    Liao, LB
    Yang, ZZ
    Ma, ZS
    Xiong, M
    ACTA CHIMICA SINICA, 2001, 59 (02) : 274 - 278
  • [5] Hydrothermal Synthesis and Structure Characterization of Open-framework Cobalt-tungsten Phosphate [H3NCH2CH2NH3]3[Co3W4P4O28]
    Zhang Yan-lin
    Yu Hai-hui
    Zhou Yang
    Hou Dian-hui
    Kong Li
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2010, 26 (06) : 862 - 865
  • [6] Hydrothermal Synthesis and Structure Characterization of Open-framework Cobalt-tungsten Phosphate [H3NCH2CH2NH3]3[Co3W4P4O28]
    ZHANG Yan-lin1
    2.College of Chemical and Materials Engineering
    Chemical Research in Chinese Universities, 2010, 26 (06) : 862 - 865
  • [7] Synthesis and characterization of a new layered vanadium selenite:: β-(H3NCH2CH2NH3)[VO)(SeO3)2]
    Dai, ZM
    Li, GH
    Shi, Z
    Fu, WS
    Dong, WJ
    Xu, J
    Feng, SH
    SOLID STATE SCIENCES, 2004, 6 (01) : 91 - 96
  • [8] Hydrothermal syntheses and structures of two novel vanadium selenites, {[VO(OH)(H2O)](SeO3)}4•2H2O and (H3NCH2CH2NH3)[(VO)(SeO3)2]
    Dai, ZM
    Shi, Z
    Li, GH
    Chen, XB
    Lu, XY
    Xu, YH
    Feng, SH
    JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (01) : 205 - 211
  • [9] A chromic molybdenum phosphate with a tunnel structure:: hydrothermal synthesis and structure of (NH3CH2CH2NH3)2 • (NH3CH2CH2NH2)3•[NaCr2Mo12O30(PO4)(HPO4)4(H2PO4)3]•6H2O
    Xu, L
    Sun, Y
    Wang, E
    Shen, E
    Liu, Z
    Hu, C
    Xing, Y
    Lin, Y
    Jia, H
    JOURNAL OF MOLECULAR STRUCTURE, 2000, 519 : 55 - 59
  • [10] A nickel molybdenum phosphate with tunnel:: Hydrothermal synthesis and structure of (NH3CH2CH2NH3)4•(NH3CH2CH2NH2)•Na•[Ni2Mo12O30(PO4)(HPO4)4(H2PO4)3]•6H2O
    Xu, L
    Sun, YQ
    Wang, EB
    Shen, EH
    Liu, ZR
    Hu, CW
    JOURNAL OF SOLID STATE CHEMISTRY, 1999, 146 (02) : 533 - 537
12345