Shale gas revolution: Catalytic conversion of C1-C3 light alkanes to value-added chemicals

被引:90
作者
Li, Xinyu [1 ,2 ]
Pei, Chunlei [1 ]
Gong, Jinlong [1 ,3 ]
机构
[1] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn, Sch Chem Engn & Technol, Key Lab Green Chem Technol,Minist Educ, Tianjin 300072, Peoples R China
[2] Univ Minnesota, Dept Chem Engn & Mat Sci, 421 Washington Ave SE, Minneapolis, MN 55455 USA
[3] Joint Sch Natl Univ Singapore & Tianjin Univ, Int Campus Tianjin Univ, Fuzhou 350207, Peoples R China
来源
CHEM | 2021年 / 7卷 / 07期
基金
美国国家科学基金会;
关键词
COPPER-EXCHANGED ZEOLITES; OXIDATIVE DEHYDROGENATION; STRUCTURE SENSITIVITY; PEROVSKITE CATALYST; ROOM-TEMPERATURE; ACTIVE-SITES; ACETIC-ACID; METHANE; NI; ACTIVATION;
D O I
10.1016/j.chempr.2021.02.002
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Shale gas is the main source and reservoir of natural gas, and contains a small fraction of ethane and propane. Along with the increasing exploitation scale, shale gas has the potential to bring about an energy revolution for the chemical industry. This paper describes the recent development for catalytic conversion of C-1-C-3 light alkanes (i.e., methane, ethane, and propane) to value-added chemicals, which involves discussions about catalyst design based on the structure-performance relationship, mechanistic analysis of reaction pathway, reactor design, and the reaction-diffusion relationship during catalytic conversion of C-1-C-3 light alkanes. Furthermore, this paper puts forward perspectives on the synthesis of catalytic materials and relevant state-of-the-art techniques.
引用
收藏
页码:1755 / 1801
页数:47
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