Shale gas revolution: Catalytic conversion of C1-C3 light alkanes to value-added chemicals

被引:90
作者
Li, Xinyu [1 ,2 ]
Pei, Chunlei [1 ]
Gong, Jinlong [1 ,3 ]
机构
[1] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn, Sch Chem Engn & Technol, Key Lab Green Chem Technol,Minist Educ, Tianjin 300072, Peoples R China
[2] Univ Minnesota, Dept Chem Engn & Mat Sci, 421 Washington Ave SE, Minneapolis, MN 55455 USA
[3] Joint Sch Natl Univ Singapore & Tianjin Univ, Int Campus Tianjin Univ, Fuzhou 350207, Peoples R China
来源
CHEM | 2021年 / 7卷 / 07期
基金
美国国家科学基金会;
关键词
COPPER-EXCHANGED ZEOLITES; OXIDATIVE DEHYDROGENATION; STRUCTURE SENSITIVITY; PEROVSKITE CATALYST; ROOM-TEMPERATURE; ACTIVE-SITES; ACETIC-ACID; METHANE; NI; ACTIVATION;
D O I
10.1016/j.chempr.2021.02.002
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Shale gas is the main source and reservoir of natural gas, and contains a small fraction of ethane and propane. Along with the increasing exploitation scale, shale gas has the potential to bring about an energy revolution for the chemical industry. This paper describes the recent development for catalytic conversion of C-1-C-3 light alkanes (i.e., methane, ethane, and propane) to value-added chemicals, which involves discussions about catalyst design based on the structure-performance relationship, mechanistic analysis of reaction pathway, reactor design, and the reaction-diffusion relationship during catalytic conversion of C-1-C-3 light alkanes. Furthermore, this paper puts forward perspectives on the synthesis of catalytic materials and relevant state-of-the-art techniques.
引用
收藏
页码:1755 / 1801
页数:47
相关论文
共 104 条
  • [1] Aqueous Au-Pd colloids catalyze selective CH4 oxidation to CH3OH with O2 under mild conditions
    Agarwal, Nishtha
    Freakley, Simon J.
    McVicker, Rebecca U.
    Althahban, Sultan M.
    Dimitratos, Nikolaos
    He, Qian
    Morgan, David J.
    Jenkins, Robert L.
    Willock, David J.
    Taylor, Stuart H.
    Kiely, Christopher J.
    Hutchings, Graham J.
    [J]. SCIENCE, 2017, 358 (6360) : 223 - 226
  • [2] Atomically dispersed nickel as coke-resistant active sites for methane dry reforming
    Akri, Mohcin
    Zhao, Shu
    Li, Xiaoyu
    Zang, Ketao
    Lee, Adam F.
    Isaacs, Mark A.
    Xi, Wei
    Gangarajula, Yuvaraj
    Luo, Jun
    Ren, Yujing
    Cui, Yi-Tao
    Li, Lei
    Su, Yang
    Pan, Xiaoli
    Wen, Wu
    Pan, Yang
    Wilson, Karen
    Li, Lin
    Qiao, Botao
    Ishii, Hirofumi
    Liao, Yen-Fa
    Wang, Aiqin
    Wang, Xiaodong
    Zhang, Tao
    [J]. NATURE COMMUNICATIONS, 2019, 10 (1)
  • [3] 2D metal carbides and nitrides (MXenes) for energy storage
    Anasori, Babak
    Lukatskaya, Maria R.
    Gogotsi, Yury
    [J]. NATURE REVIEWS MATERIALS, 2017, 2 (02):
  • [4] Oxidation of methane by a biological dicopper centre
    Balasubramanian, Ramakrishnan
    Smith, Stephen M.
    Rawat, Swati
    Yatsunyk, Liliya A.
    Stemmler, Timothy L.
    Rosenzweig, Amy C.
    [J]. NATURE, 2010, 465 (7294) : 115 - U131
  • [5] Oxidative coupling of methane-A complex surface/gas phase mechanism with strong impact on the reaction engineering
    Beck, Benjamin
    Fleischer, Vinzenz
    Arndt, Sebastian
    Gonzalez Hevia, Miguel
    Urakawa, Atsushi
    Hugo, Peter
    Schomaecker, Reinhard
    [J]. CATALYSIS TODAY, 2014, 228 : 212 - 218
  • [6] CH4 dehydroaromatization on Mo/H-ZSM-5: 1. Effects of co-processing H2 and CH3COOH
    Bedard, Jeremy
    Hong, Do-Young
    Bhan, Aditya
    [J]. JOURNAL OF CATALYSIS, 2013, 306 : 58 - 67
  • [7] Entropy considerations in monomolecular cracking of alkanes on acidic zeolites
    Bhan, Aditya
    Gounder, Rajamani
    Macht, Josef
    Iglesia, Enrique
    [J]. JOURNAL OF CATALYSIS, 2008, 253 (01) : 221 - 224
  • [8] Converting olefins to propene: Ethene to propene and olefin cracking
    Blay, Vincent
    Epelde, Eva
    Miravalles, Ruben
    Alvarado Perea, Leo
    [J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2018, 60 (02): : 278 - 335
  • [9] Shale Gas Revolution: An Opportunity for the Production of Biobased Chemicals?
    Bruijnincx, Pieter C. A.
    Weckhuysen, Bert M.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (46) : 11980 - 11987
  • [10] Monomolecular cracking of propane over acidic chabazite: An ab initio molecular dynamics and transition path sampling study
    Bucko, Tomas
    Benco, Lubomir
    Hafner, Juergen
    Angyan, Janos G.
    [J]. JOURNAL OF CATALYSIS, 2011, 279 (01) : 220 - 228