The synthesis of nanocellulose-based nanocomposites for the effective removal of hexavalent chromium ions from aqueous solution

被引:6
作者
Alzahrani, Fatimah Mohammed [1 ]
Amari, Abdelfattah [2 ,3 ]
Katubi, Khadijah Mohammedsaleh [1 ]
Alsaiari, Norah Salem [1 ]
Tahoon, Mohamed A. [4 ,5 ]
机构
[1] Princess Nourah bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia
[2] King Khalid Univ, Coll Engn, Dept Chem Engn, Abha 61411, Saudi Arabia
[3] Gabes Univ, Natl Sch Engineers, Res Lab Proc Energet Environm & Elect Syst, Dept Chem Engn & Proc, Gabes 6072, Tunisia
[4] King Khalid Univ, Coll Sci, Dept Chem, POB 9004, Abha 61413, Saudi Arabia
[5] Mansoura Univ, Fac Sci, Chem Dept, Mansoura 35516, Egypt
来源
OPEN CHEMISTRY | 2022年 / 20卷 / 01期
关键词
nanocomposites; nanocellulose; polydopamine; adsorption; water treatment; hexavalent chromium ions; EFFICIENT REMOVAL; SURFACE MODIFICATION; CR(VI) IONS; ADSORPTION; ADSORBENT; WASTE; WATER; CONTAMINANTS; PERFORMANCE; COMPOSITE;
D O I
10.1515/chem-2022-0215
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present study reports the synthesis of a polydopamine (PDA)/nanocellulose (NC) nanocomposite for the effective removal of chromium ions from water. PDA was used to modify NC surface producing a nanocomposite namely PDA/NC, by in situ polymerization of dopamine on the surface of NC. Thereafter, the as-synthesized nanocomposite was characterized using familiar techniques such as Fourier transform infrared, X-ray diffraction, X-ray photoelectron spectroscopy, ultraviolet-visible spectroscopy, and transmission electron microscopy. All results indicated the successful combination of PDA and NC in one nanocomposite. The PDA/NC nanocomposite was evaluated for the removal of hexavalent Cr(vi) ions from an aqueous solution. The adsorption conditions, such as pH, contact time, and initial Cr(vi) concentration, were optimized. Adsorption kinetic studies revealed that Cr(vi) removal on the surface of PDA/NC nanocomposite followed the pseudo-second-order kinetic model. Furthermore, isotherm studies revealed that Cr(vi) removal followed the Langmuir isotherm model with a maximum adsorption capacity (q (m)) of 210 mg/g. The adsorption mechanism study indicated that the Cr(vi) removal was reached via complexation, adsorption, and chemical reduction. The reusability of a PDA/NC nanocomposite for the removal of Cr(vi) ions was studied up to five cycles with acceptable results. The high adsorption capacity and multiple removal mechanisms validated the effective applicability of PDA/NC nanocomposite as a useful adsorbent for the removal of Cr(vi) ions from aqueous solution.
引用
收藏
页码:970 / 983
页数:14
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