The Cr-doping effect on white light emitting properties of Ce:YAG phosphor ceramics

被引：62
作者：
Tang, Yanru [1 ,2 ]
Zhou, Shengming [1 ]
Yi, Xuezhuan [1 ]
Zhang, Shuai [1 ]
Hao, Deming [1 ,3 ]
Shao, Xiuchen [1 ,3 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai, Peoples R China
[2] Univ Chinese Acad Sci, Beijing, Peoples R China
[3] Shanghai Tech Univ, Shanghai, Peoples R China
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2017年 / 100卷 / 06期
基金：
中国国家自然科学基金;
关键词：
dopants; doping; fluorescence; impurities; transparent ceramics; yttrium aluminum garnet; TRANSPARENT CERAMICS; LUMINESCENCE; Y3AL5O12;
D O I：
10.1111/jace.14717
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The Cr/Ce-doped YAG transparent ceramic was fabricated by the solid-state reaction in vacuum. The Cr/Ce-doped YAG ceramic phosphor effectively complement the red spectral component and improve the color rendering performance when excited by blue light that is due to the effective energy transfer between Cr3+ ion and Ce3+ ion. However, the energy transfer from Ce3+ to Cr3+ ion leads to energy loss and therefore the luminous efficacy of the WLED which is composed of blue LED chip and the Cr/Ce-doped YAG ceramic phosphor decreases. The composite phase structure of ceramic phosphor is designed for improving the extraction efficacy and increasing the luminous efficacy by breaking the total internal reflection (TIR) at the interface between air and ceramic.
引用
收藏
页码：2590 / 2595
页数：6
相关论文
共 18 条
  • [1] Structural effects and 4f-5d transition shifts induced by La codoping in Ce-doped yttrium aluminum garnet: First-principles study
    Belen Munoz-Garcia, Ana
    Luis Pascual, Jose
    Barandiaran, Zoila
    Seijo, Luis
    [J]. PHYSICAL REVIEW B, 2010, 82 (06)
  • [2] Microstructural Evolution During Vacuum Sintering of Yttrium Aluminum Garnet Transparent Ceramics: Toward the Origin of Residual Porosity Affecting the Transparency
    Boulesteix, Remy
    Maitre, Alexandre
    Chretien, Lucie
    Rabinovitch, Yoel
    Salle, Christian
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2013, 96 (06) : 1724 - 1731
  • [3] Transparent Ce3+: Y3Al5O12 glass ceramic for organic-resin-free white-light-emitting diodes
    Chen, Daqin
    Chen, Yan
    [J]. CERAMICS INTERNATIONAL, 2014, 40 (09) : 15325 - 15329
  • [4] Luminescence Characteristics of YAG Glass-Ceramic Phosphor for White LED
    Fujita, Shunsuke
    Sakamoto, Akihiko
    Tanabe, Setsuhisa
    [J]. IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, 2008, 14 (05) : 1387 - 1391
  • [5] Improvement of electroluminescent property of blue LED coated with highly luminescent yellow-emitting phosphors
    Jang, H. S.
    Won, Y. -H.
    Jeon, D. Y.
    [J]. APPLIED PHYSICS B-LASERS AND OPTICS, 2009, 95 (04): : 715 - 720
  • [6] Properties of transparent Ce:YAG ceramic phosphors for white LED
    Nishiura, S.
    Tanabe, S.
    Fujioka, K.
    Fujimoto, Y.
    [J]. OPTICAL MATERIALS, 2011, 33 (05) : 688 - 691
  • [7] Tailored photoluminescence of YAG:Ce phosphor through various methods
    Pan, YX
    Wu, MM
    Su, Q
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2004, 65 (05) : 845 - 850
  • [8] Pust P, 2014, NAT MATER, V13, P891, DOI [10.1038/nmat4012, 10.1038/NMAT4012]
  • [9] Efficient energy transfer between Ce3+/Cr3+ and Nd3+ ions in transparent Nd/Ce/Cr:YAG ceramics
    Samuel, P.
    Kumar, G. A.
    Yanagitani, Takagimi
    Yagi, Hideki
    Ueda, Ken Ichi
    Babu, S. Moorthy
    [J]. OPTICAL MATERIALS, 2011, 34 (01) : 303 - 307
  • [10] Fabrication and Luminescence Study of Ce3+-doped YAG Transparent Ceramics
    Shi Yun
    Pan Yu-Bai
    Feng Xi-Qi
    Li Jiang
    Guo Jin-Kun
    [J]. JOURNAL OF INORGANIC MATERIALS, 2010, 25 (02) : 125 - 128
12