Preparation of MoS2-MoO3 Hybrid Nanomaterials for Light-Emitting Diodes

被引：175

作者：

Yin, Zongyou ^{[1
]}

Zhang, Xiao ^{[1
]}

Cai, Yongqing ^{[2
]}

Chen, Junze ^{[1
]}

Wong, Jen It ^{[4
]}

Tay, Yee-Yan ^{[1
]}

Chai, Jianwei ^{[3
]}

Wu, Jumiati ^{[1
]}

Zeng, Zhiyuan ^{[1
]}

Zheng, Bing ^{[1
]}

Yang, Hui Ying ^{[4
]}

Zhang, Hua ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] ASTAR, Inst High Performance Comp, Singapore 138632, Singapore

[3] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore

[4] Singapore Univ Technol & Design, Singapore 138682, Singapore

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 46期

基金：

新加坡国家研究基金会;

关键词：

electroluminescence; hybrid nanomaterials; light-emitting diodes; molybdenum; p-type doping; MOLYBDENUM-DISULFIDE; LARGE-AREA; LAYER; HETEROSTRUCTURES; TRANSISTORS; GRAPHENE; PHOTOLUMINESCENCE; IDENTIFICATION; EVOLUTION; MOO3;

D O I：

10.1002/anie.201402935

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile strategy to prepare MoS2-MoO3 hybrid nanomaterials is developed, based on the heat-assisted partial oxidation of lithium-exfoliated MoS(2)nanosheets in air followed by thermal-annealing-driven crystallization. The obtained MoS2-MoO3 hybrid nanomaterial exhibits p-type conductivity. As a proof-of-concept application, an n-typeSiC/p-typeMoS(2)-MoO3 heterojunction is used as the active layer for light-emitting diodes. The origins of the electroluminescence from the device are theoretically investigated. This facile synthesis and application of hybrid nanomaterials opens up avenues to develop new advanced materials for various functional applications, such as in electrics, optoelectronics, clean energy, and information storage.

引用

页码：12560 / 12565

页数：6

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