Recovery of thorium (IV) from leached monazite solutions using counter-current extraction

被引:29
作者
Ali, A. M. I. [1 ]
El-Nadi, Y. A. [1 ]
Daoud, J. A. [1 ]
Aly, H. F. [1 ]
机构
[1] Atom Energy Author, Hot Labs Ctr, Cairo, Egypt
关键词
monazite; alkaline leaching; thorium; Aliquat-336; mixer-settler;
D O I
10.1016/j.minpro.2006.06.006
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A flow sheet was developed to recover thorium from Egyptian monazite sands. The results of a detailed investigation on the extraction and stripping of thorium in the hydrous oxide are obtained after alkaline dissolution followed by leaching with alkaline carbonate solutions. This cake was dissolved in 4 M HNO3 and thorium was extracted selectively by a counter-current extraction system using a mixer-settler contactor and Aliquat-336 in kerosene as extractant. The results show that 2 h of continuous operation are necessary to reach the steady state condition for the process. The extraction efficiency is found to be 80% and the stripping efficiency is 82%. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:217 / 223
页数:7
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