Silica-supported aluminum chloride: A recyclable and reusable catalyst for one-pot three-component Mannich-type reactions

被引:110
作者
Li, Zheng [1 ]
Ma, Xuelin [1 ]
Liu, Jing [1 ]
Feng, Xu [1 ]
Tian, Guoqiang [1 ]
Zhu, Anguo [1 ]
机构
[1] NW Normal Univ, Coll Chem & Chem Engn, Gansu Key Lab Polymer Mat, Lanzhou 730070, Gansu, Peoples R China
关键词
Mannich reaction; silica-supported aluminum chloride; beta-aminocarbonyl compound; one-pot reaction;
D O I
10.1016/j.molcata.2007.03.029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Silica-supported aluminum chloride was used as an efficient, recyclable and reusable catalyst for the one-pot Mannich-type reactions of acetophenone with aromatic aldehydes and aromatic amines. This protocol has advantages of high yield, mild condition, no environmental pollution, and simple work-up procedure. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:132 / 135
页数:4
相关论文
共 29 条
[1]   HCl-catalyzed stereoselective Mannich reaction in H2O-SDS system [J].
Akiyama, T ;
Matsuda, K ;
Fuchibe, K .
SYNLETT, 2005, (02) :322-324
[2]   Enantioselective Mannich-type reaction catalyzed by a chiral Bronsted acid [J].
Akiyama, T ;
Itoh, J ;
Yokota, K ;
Fuchibe, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (12) :1566-1568
[3]   Mannich-type reaction catalyzed by HBF4 in water:: Effect of the loading of surfactant [J].
Akiyama, T ;
Itoh, J ;
Fuchibe, K .
SYNLETT, 2002, (08) :1269-1272
[4]  
Akiyama T, 1999, SYNLETT, P1426
[5]   HBF4 catalyzed Mannich-type reaction in aqueous media [J].
Akiyama, T ;
Takaya, J ;
Kagoshima, H .
SYNLETT, 1999, (07) :1045-1048
[6]  
Arend M, 1998, ANGEW CHEM INT EDIT, V37, P1044, DOI 10.1002/(SICI)1521-3773(19980504)37:8<1044::AID-ANIE1044>3.0.CO
[7]  
2-E
[8]   Highly efficient one-pot three-component Mannich reaction in water catalyzed by heteropoly acids [J].
Azizi, N ;
Torkiyan, L ;
Saidi, MR .
ORGANIC LETTERS, 2006, 8 (10) :2079-2082
[9]   ENVIRONMENTALLY FRIENDLY CATALYSIS USING SUPPORTED REAGENTS - EVOLUTION OF A HIGHLY-ACTIVE FORM OF IMMOBILIZED ALUMINUM-CHLORIDE [J].
CLARK, JH ;
MARTIN, K ;
TEASDALE, AJ ;
BARLOW, SJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) :2037-2040
[10]   Copper(I)-fesulphos Lewis acid catalysts for enantioselective Mannich-type reaction of N-sulfonyl imines [J].
Gonzalez, Alvaro Salvador ;
Arrayas, Ramon Gomez ;
Carretero, Juan C. .
ORGANIC LETTERS, 2006, 8 (14) :2977-2980