Solvent-dependent selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under neat conditions

被引：46
作者：
Liu, Kai-Jian [1 ]
Zeng, Tang-Yu [1 ]
Zeng, Jia-Le [1 ]
Gong, Shao-Feng [1 ]
He, Jun-Yi [2 ]
Lin, Ying-Wu [4 ]
Tan, Jia-Xi [3 ]
Cao, Zhong [2 ]
He, Wei-Min [1 ,2 ]
机构：
[1] Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China
[2] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China
[3] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China
[4] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2019年 / 30卷 / 12期
关键词：
5-Hydroxymethylfurfural; 2,5-Furandicarboxylic acid; Base-free; External initiator-free; Dioxygen; INDUCED DEOXYGENATIVE C2-SULFONYLATION; QUINOLINE N-OXIDES; AEROBIC OXIDATION; CATALYST; CYCLIZATION; ALCOHOL; KETONES; AMINES; BASE;
D O I：
10.1016/j.cclet.2019.10.031
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An eco-friendly and economical route for the oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) with atmospheric dioxygen as the sole oxidant under acid-, base-, metal-, and external initiator-free conditions in minimal solvent was reported. In the present reaction, the 1,2-diethoxyethylane has a dual role: reaction medium and free-radical initiator. The FDCA easily crystallizes during the reaction and was simple purified via recrystallization to provide the pure FDCA. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：2304 / 2308
页数：5
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