Solvent-dependent selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under neat conditions

被引：43
|
作者：
Liu, Kai-Jian [1 ]
Zeng, Tang-Yu [1 ]
Zeng, Jia-Le [1 ]
Gong, Shao-Feng [1 ]
He, Jun-Yi [2 ]
Lin, Ying-Wu [4 ]
Tan, Jia-Xi [3 ]
Cao, Zhong [2 ]
He, Wei-Min [1 ,2 ]
机构：
[1] Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China
[2] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China
[3] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China
[4] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2019年 / 30卷 / 12期
关键词：
5-Hydroxymethylfurfural; 2,5-Furandicarboxylic acid; Base-free; External initiator-free; Dioxygen; INDUCED DEOXYGENATIVE C2-SULFONYLATION; QUINOLINE N-OXIDES; AEROBIC OXIDATION; CATALYST; CYCLIZATION; ALCOHOL; KETONES; AMINES; BASE;
D O I：
10.1016/j.cclet.2019.10.031
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An eco-friendly and economical route for the oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) with atmospheric dioxygen as the sole oxidant under acid-, base-, metal-, and external initiator-free conditions in minimal solvent was reported. In the present reaction, the 1,2-diethoxyethylane has a dual role: reaction medium and free-radical initiator. The FDCA easily crystallizes during the reaction and was simple purified via recrystallization to provide the pure FDCA. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：2304 / 2308
页数：5
相关论文
共 50 条
  • [1] Solvent-dependent selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under neat conditions
    Kai-Jian Liu
    Tang-Yu Zeng
    Jia-Le Zeng
    Shao-Feng Gong
    Jun-Yi He
    Ying-Wu Lin
    Jia-Xi Tan
    Zhong Cao
    Wei-Min He
    Chinese Chemical Letters, 2019, 30 (12) : 2304 - 2308
  • [2] Aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid in water under mild conditions
    Liu, Bing
    Ren, Yongshen
    Zhang, Zehui
    GREEN CHEMISTRY, 2015, 17 (03) : 1610 - 1617
  • [3] A novel platinum nanocatalyst for the oxidation of 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic acid under mild conditions
    Siankevich, Sviatlana
    Savoglidis, Georgios
    Fei, Zhaofu
    Laurenczy, Gabor
    Alexander, Duncan T. L.
    Yan, Ning
    Dyson, Paul J.
    JOURNAL OF CATALYSIS, 2014, 315 : 67 - 74
  • [4] NiFeCo wrinkled nanosheet electrode for selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
    Chen, Bingkun
    Yang, Bowen
    Su, Yaqiong
    Hou, Qidong
    Smith Jr, Richard Lee
    Qi, Xinhua
    Guo, Haixin
    GREEN CHEMISTRY, 2025, 27 (07) : 2117 - 2129
  • [5] Cu catalyzed oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran and 2,5-furandicarboxylic acid under benign reaction conditions
    Hansen, Thomas S.
    Sadaba, Irantzu
    Garcia-Suarez, Eduardo J.
    Riisager, Anders
    APPLIED CATALYSIS A-GENERAL, 2013, 456 : 44 - 50
  • [6] Ru/MgO-catalysed selective aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
    Lokhande, Priya
    Dhepe, Paresh L.
    Wilson, Karen
    Lee, Adam F.
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2024, 77 (10)
  • [7] A Facile Synthesis Route to AuPd Alloys for the Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid
    Peng, Yani
    Qiu, Boya
    Ding, Shengzhe
    Hu, Min
    Zhang, Yuxin
    Jiao, Yilai
    Fan, Xiaolei
    Parlett, Christopher M. A.
    CHEMPLUSCHEM, 2024, 89 (01):
  • [8] Heterogeneous Catalysis for Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid under Base-Free Conditions
    Meng, Zheng-Zheng
    Chen, Shan-Shan
    Li, Hong-Ru
    He, Liang-Nian
    CHEMCATCHEM, 2024,
  • [9] Kinetic Modeling of Homogenous Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid
    Wei, Zange
    Li, Wenhao
    Yuan, Fang
    Sun, Weizhen
    Zhao, Ling
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (50) : 18352 - 18361
  • [10] On the mechanism of selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over supported Pt and Au catalysts
    Davis, Sara E.
    Zope, Bhushan N.
    Davis, Robert J.
    GREEN CHEMISTRY, 2012, 14 (01) : 143 - 147
12345