Metal-coated microcapsules with tunable magnetic properties synthesized via electroless plating

被引:15
作者
Tsuneyoshi, Toshihiko [1 ]
Ono, Tsutomu [1 ]
机构
[1] Okayama Univ, Grad Sch Nat Sci & Technol, Dept Appl Chem, Kita Ku, 3-1-1 Tsushima Naka, Okayama 7008530, Japan
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2017年 / 222卷
关键词
Microencapsulation; Electroless Ni plating; Magnetic response; Superparamagnetism; Ferromagnetis; PHASE-CHANGE MATERIAL; POLYELECTROLYTE MICROCAPSULES; INTERFACIAL POLYMERIZATION; CORE-SHELL; PARTICLES; MICROENCAPSULATION; CAPSULES; MICROSPHERES; SYSTEM;
D O I
10.1016/j.mseb.2017.04.009
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Metal-coated microcapsules with tunable magnetic properties, which contained liquid cores and metallic Ni-P alloy shells, were synthesized via electroless plating. The fabrication process consisted of emulsification, phase separation, and electroless Ni plating stages. The material composition and sizes of Ni single crystals in the obtained metallic shells depended on the pH of the plating solution. It was found that the microcapsules prepared at high pH values (8.0 and 10.0) were characterized by ferromagnetic properties, whereas those synthesized at low pH values (4.7 and 6.0) were superparamagnetic. The produced micro capsules have potential applications as magnetic responsive carriers of phase change materials, which can be easily transferred to a desired place by applying external magnetic field. (c) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:49 / 54
页数:6
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