Structure and growth mechanism of CuO plates obtained by microwave-hydrothermal without surfactants

被引：113
作者：
Moura, A. P. [2 ]
Cavalcante, L. S. [1 ]
Sczancoski, J. C. [2 ]
Stroppa, D. G. [3 ]
Paris, E. C. [2 ]
Ramirez, A. J. [3 ]
Varela, J. A. [1 ]
Longo, E. [1 ]
机构：
[1] Univ Estadual Paulista, LIEC IQ, BR-14801907 Araraquara, SP, Brazil
[2] Univ Fed Sao Carlos, LIEC DQ, BR-13565905 Sao Carlos, SP, Brazil
[3] Lab Nacl Luz Sincrotron, BR-13083970 Campinas, SP, Brazil
来源：
ADVANCED POWDER TECHNOLOGY | 2010年 / 21卷 / 02期
基金：
巴西圣保罗研究基金会;
关键词：
CuO; Plates; Rietveld refinement; Microscopy; Crystal growth; ELECTRODE MATERIALS; CUPRIC OXIDE; POWDER DIFFRACTION; ASSISTED SYNTHESIS; NANOSTRUCTURES; NANOPARTICLES; CU2O; OXIDATION; ROUTE; AGGREGATION;
D O I：
10.1016/j.apt.2009.11.007
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
CuO plates were obtained by microwave-hydrothermal processing at 130 C for 30 min without any surfactant. X-ray diffraction, Rietveld refinement and selected area electron diffraction showed that the CuO plates present a monoclinic structure without secondary phases. The nitrogen adsorption isotherm measurements revealed a specific surface area of approximately 30 m(2)/g. Field-emission gun scanning electron microscopy and transmission electron microscope micrographs indicated that the growth process of these plates was through Ostwald ripening and aggregation of plates surface by Van der Waals forces along to the two [100] and [010] directions. (C) 2009 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
引用
收藏
页码：197 / 202
页数：6
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共 67 条
  • [1] APPLICATION OF MICROWAVE-HEATING TECHNIQUES FOR THE SYNTHESIS OF SOLID-STATE INORGANIC-COMPOUNDS
    BAGHURST, DR
    MINGOS, DMP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (12) : 829 - 830
  • [2] CuO, ZrO2 and ZnO nanoparticles as antiwear additive in oil lubricants
    Battez, A. Hernandez
    Gonzalez, R.
    Viesca, J. L.
    Fernandez, J. E.
    Fernandez, J. M. Diaz
    Machado, A.
    Chou, R.
    Riba, J.
    [J]. WEAR, 2008, 265 (3-4) : 422 - 428
  • [3] Adsorption of gases in multimolecular layers
    Brunauer, S
    Emmett, PH
    Teller, E
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 : 309 - 319
  • [4] Growth mechanism of octahedron-like BaMoO4 microcrystals processed in microwave-hydrothermal: Experimental observations and computational modeling
    Cavalcante, Laecio Santos
    Sczancoski, Julio Cesar
    Tranquilin, Rircado Luis
    Varela, Jose Arana
    Longo, Elson
    Orlandi, Marcelo Ornaghi
    [J]. PARTICUOLOGY, 2009, 7 (05) : 353 - 362
  • [5] Controlled synthesis and. self-assembly of single-crystalline CuO nanorods and nanoribbons
    Chang, Y
    Zeng, HC
    [J]. CRYSTAL GROWTH & DESIGN, 2004, 4 (02) : 397 - 402
  • [6] CuO nanowires synthesized by thermal oxidation route
    Chen, J. T.
    Zhang, F.
    Wang, J.
    Zhang, G. A.
    Miao, B. B.
    Fan, X. Y.
    Yan, D.
    Yan, P. X.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 454 (1-2) : 268 - 273
  • [7] Growth of hex-pod-like Cu2O whisker under hydrothermal conditions
    Chen, ZZ
    Shi, EW
    Zheng, YQ
    Li, WJ
    Xiao, B
    Zhuang, JY
    [J]. JOURNAL OF CRYSTAL GROWTH, 2003, 249 (1-2) : 294 - 300
  • [8] Response speed of SnO2-based H2S gas sensors with CuO nanoparticles
    Chowdhuri, A
    Gupta, V
    Sreenivas, K
    Kumar, R
    Mozumdar, S
    Patanjali, PK
    [J]. APPLIED PHYSICS LETTERS, 2004, 84 (07) : 1180 - 1182
  • [9] A CORRECTION FOR POWDER DIFFRACTION PEAK ASYMMETRY DUE TO AXIAL DIVERGENCE
    FINGER, LW
    COX, DE
    JEPHCOAT, AP
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 : 892 - 900
  • [10] Chemical synthesis, characterisation and gas sensing performance of copper oxide nanoribbons
    Gou, Xinglong
    Wang, Guoxiu
    Yang, Juan
    Park, Jinsoo
    Wexler, David
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (09) : 965 - 969
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