Iron-Catalyzed Direct Arylation through an Aryl Radical Transfer Pathway

被引：171

作者：

Vallee, Frederic ^{[1
]}

Mousseau, James J. ^{[1
]}

Charette, Andre B. ^{[1
]}

机构：

[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 05期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

CROSS-COUPLING REACTIONS; C-H BONDS; HETEROAROMATIC-COMPOUNDS; UNACTIVATED ARENES; SELF-ORGANIZATION; POLYMERIZATION; HETEROCYCLES; ACTIVATION; REAGENTS; CLEAVAGE;

D O I：

10.1021/ja910687u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general and efficient iron-catalyzed direct arylation of benzene and hetereoaryl derivatives using a cost-effective and environmentally benign catalyst is described. The reaction is performed under neat conditions and can proceed at room temperature.

引用

页码：1514 / +

页数：4

共 44 条

[1] Ruthenium-Catalyzed Regioselective Direct Alkylation of Arenes with Unactivated Alkyl Halides through C-H Bond Cleavage [J].

Ackermann, Lutz ;

Novak, Petr ;

Vicente, Ruben ;

Hofmann, Nora .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (33) :6045-6048

[2] Aryl-aryl bond formation by transition-metal-catalyzed direct arylation [J].

Alberico, Dino ;

Scott, Mark E. ;

Lautens, Mark .

CHEMICAL REVIEWS, 2007, 107 (01) :174-238

[3]

Anslyn E. V., 2006, MODERN PHYS ORGANIC

[4] Iron-catalyzed C-O cross-couplings of phenols with aryl iodides [J].

Bistri, Olivia ;

Correa, Arkaitz ;

Bolm, Carsten .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :586-588

[5] Iron-catalyzed reactions in organic synthesis [J].

Bolm, C ;

Legros, J ;

Le Paih, J ;

Zani, L .

CHEMICAL REVIEWS, 2004, 104 (12) :6217-6254

[6] On the Role of Metal Contaminants in Catalyses with FeCl3 [J].

Buchwald, Stephen L. ;

Bolm, Carsten .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (31) :5586-5587

[7] Mild Ullmann-type biaryl ether formation reaction by combination of ortho-substituent and ligand effects [J].

Cai, Q ;

Zou, BL ;

Ma, DW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (08) :1276-1279

[8]

CAMPEAU LC, 2006, CHEM SOC REV, V36, P1173

[9] Iron-catalyzed S-arylation of thiols with aryl iodides [J].

Correa, Arkaitz ;

Carril, Monica ;

Bolm, Carsten .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (15) :2880-2883

[10] Iron-catalysed carbon-heteroatom and heteroatom-heteroatom bond forming processes [J].

Correa, Arkaitz ;

Mancheno, Olga Garcia ;

Bolm, Carsten .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (06) :1108-1117

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