Switching of molecular spin states in inorganic complexes by temperature, pressure, magnetic field and light:: Towards molecular devices

被引：200

作者：

Bousseksou, A

Molnár, G

Matouzenko, G

机构：

[1] Ecole Normale Super Lyon, Chim Lab, CNRS, UMR, F-69364 Lyon, France

[2] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 22期

关键词：

spin crossover; metastability; hysteresis loop; pressure; magnetic field; dielectric properties; ising-like model;

D O I：

10.1002/ejic.200400571

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The spin crossover phenomenon in molecular inorganic compounds is one of the most spectacular examples of bistability phenomena leading to a switching between the high-spin and the low-spin states of the molecule by several means such as temperature, pressure, light and magnetic field (multi-property molecular switching). In the present micro-review we report our most important findings, both experimental results and theoretical approaches, and discuss possible technological applications for each switching method as well as the recent synthesis of new spin crossover molecular materials.

引用

页码：4353 / 4369

页数：17

共 109 条

[71] Spin transition in [Fe(DPEA)(NCS)(2)], a compound with the new tetradentate ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (DPEA): Crystal structure, magnetic properties, and Mossbauer spectroscopy
Matouzenko, GS
Bousseksou, A
Lecocq, S
vanKoningsbruggen, PJ
Perrin, M
Kahn, O
Collet, A
[J]. INORGANIC CHEMISTRY, 1997, 36 (14) : 2975 - 2981
[72] PHOTOCHEMICALLY-INDUCED PERTURBATION OF THE 1A-REVERSIBLE-5T EQUILIBRIUM IN FE-II COMPLEXES BY PULSED LASER IRRADIATION IN THE METAL-TO-LIGAND CHARGE-TRANSFER ABSORPTION-BAND
MCGARVEY, JJ
LAWTHERS, I
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (16) : 906 - 907
[73] SPIN-STATE RELAXATION DYNAMICS IN IRON(II) COMPLEXES - SOLVENT EFFECTS ON THE ACTIVATION AND REACTION VOLUMES FOR THE 1A REVERSIBLE 5T INTERCONVERSION
MCGARVEY, JJ
LAWTHERS, I
HEREMANS, K
TOFTLUND, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (23) : 1575 - 1576
[74] ANOMALOUS PRESSURE-DEPENDENCE OF THE LAMB-MOSSBAUER FACTOR IN A SPIN CROSSOVER SYSTEM
MEISSNER, E
KOPPEN, H
KOHLER, CP
SPIERING, H
GUTLICH, P
[J]. HYPERFINE INTERACTIONS, 1986, 28 (1-4): : 799 - 801
[75] EXAFS AND X-RAY-POWDER DIFFRACTION STUDIES OF THE SPIN TRANSITION MOLECULAR MATERIALS [FE(HTRZ)A(TRZ)](BF4) AND [FE(HTRZ)(3)](BF4)(2)CENTER-DOT-H2O (HTRZ=1,2,4-4H-TRIAZOLE, TRZ=1,2,4-TRIAZOLATO)
MICHALOWICZ, A
MOSCOVICI, J
DUCOURANT, B
CRACCO, D
KAHN, O
[J]. CHEMISTRY OF MATERIALS, 1995, 7 (10) : 1833 - 1842
[76] MICHALOWICZ A, 1997, J PHYS IV, V7, pC2
[77] STRUCTURE CHANGES AND THE SPIN PHASE-TRANSITION MECHANISM OF A SPIN CROSSOVER COMPLEX, [FE(2-PIC)3]CL2.ETOH
MIKAMI, M
KONNO, M
SAITO, Y
[J]. CHEMICAL PHYSICS LETTERS, 1979, 63 (03) : 566 - 569
[78] Mass effect on the equienergetic high-spin/low-spin states of spin-crossover in 4,4′-bipyridine-bridged iron(II) polymeric compounds:: Synthesis, structure, and magnetic, Mossbauer, and theoretical studies
Molíner, N
Muñoz, MC
Létard, S
Salmon, L
Tuchagues, JP
Bousseksou, A
Real, JA
[J]. INORGANIC CHEMISTRY, 2002, 41 (26) : 6997 - 7005
[79] Thermal and optical switching of molecular spin states in the {FeL[H2B(pz)2]2} spin-crossover system (L = bpy, phen)
Moliner, N
Salmon, L
Capes, L
Muñoz, MC
Létard, JF
Bousseksou, A
Tuchagues, JP
McGarvey, JJ
Dennis, AC
Castro, M
Burriel, R
Real, JA
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (16) : 4276 - 4283
[80] Spin crossover bistability in three mutually perpendicular interpenetrated (4,4) nets
Moliner, N
Muñoz, C
Létard, S
Solans, X
Menéndez, N
Goujon, A
Varret, F
Real, JA
[J]. INORGANIC CHEMISTRY, 2000, 39 (23) : 5390 - +

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