A convenient synthesis of high-loaded palladium(II) ROMP polymers

被引：7

作者：

Braddock, DC ^{[1
]}

Chadwick, D

Lindner-López, E

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, London SW7 2AZ, England

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 49期

关键词：

palladium(II); ROMP; ROMP polymer;

D O I：

10.1016/j.tetlet.2004.10.056

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis[1-(5-norbornen-2-yl)butan-1,3-dionato]palladium(II) was conveniently prepared from 5-acetoacetyl-2-norbornene and sodium tetrachloropalladate. The former could be subjected to ROMP to give a highly-loaded palladium(II) ROMP polymer with a palladium loading of 23% by weight. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：9021 / 9024

页数：4

共 18 条

[1] ROMPgel reagents in parallel synthesis [J].

Barrett, AGM ;

Hopkins, BT ;

Köbberling, J .

CHEMICAL REVIEWS, 2002, 102 (10) :3301-3323

[2]

BRIGGS D, 1990, PRACTICAL SURFACE AN, V1

[3] Synthesis and copolymerization of rhodium(I) and palladium(II) complexes with the deprotonated form of 2-(acetoacetoxy)ethyl methacrylate [J].

Dell'Anna, MM ;

Mastrorilli, P ;

Rizzuti, A ;

Suranna, GP ;

Nobile, CF .

INORGANICA CHIMICA ACTA, 2000, 304 (01) :21-25

[4]

Dell'Anna MM, 2002, EUR J INORG CHEM, P1094

[5] Asymmetric allylic alkylation using a polymer-supported palladium catalyst in the presence of chiral ligands [J].

Dell'Anna, MM ;

Mastrorilli, P ;

Nobile, CF ;

Suranna, GP .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 201 (1-2) :131-135

[6] Hydrogenation reactions catalysed by a supported palladium complex [J].

Dell'Anna, MM ;

Gagliardi, M ;

Mastrorilli, P ;

Suranna, GP ;

Nobile, CF .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 158 (02) :515-520

[7] Heck reactions between aryl halides and olefins catalysed by Pd-complexes entrapped into zeolites NaY [J].

Djakovitch, L ;

Heise, W ;

Köhler, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 584 (01) :16-26

[8] Enantioselective synthesis of cyclothiazide analogues: Novel probes of the stereospecific actions of benzothiadiazines at AMPA-type glutamate receptors [J].

Hu, YF ;

Yamada, KA ;

Chalmers, DK ;

Annavajjula, DP ;

Covey, DF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (19) :4550-4559

[9] ENZYMATIC RESOLUTION OF NORBOR(NE)NYLMETHANOLS IN ORGANIC MEDIA AND AN APPLICATION TO THE SYNTHESIS OF (+)-ENDO-NORBORNENE AND (-)-ENDO-NORBORNENE LACTONE [J].

JANSSEN, AJM ;

KLUNDER, AJH ;

ZWANENBURG, B .

TETRAHEDRON, 1991, 47 (29) :5513-5538

[10] O,O'-CHELATE AND CENTRAL-CARBON-BONDED COMPLEXES OF ETHYL ACETOACETATE WITH PALLADIUM(II) [J].

OKEY, S ;

KAWAGUCHI, S .

INORGANIC CHEMISTRY, 1977, 16 (07) :1730-1736

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