Eco-friendly elimination of organic pollutants from water using graphene oxide assimilated magnetic nanoparticles adsorbent

被引:10
作者
Khan, Muhammad Farooq [1 ]
Jamal, Adil [2 ]
Rosy, P. Jacquline [3 ]
Alguno, Arnold C. [4 ]
Ismail, Muhammad [5 ]
Khan, Imran [6 ]
Ismail, Ahmed [7 ]
Zahid, Muhammad [7 ,8 ]
机构
[1] Univ Peshawar, Inst Chem Sci, Peshawar 25120, Khyber Pakhtunk, Pakistan
[2] Umm Al Qura Univ, Sci & Res Coll Nursing, 715, Mecca, Saudi Arabia
[3] IFET Coll Engn Autonomous Gangarampalayam, Dept Chem, Villupuram 605108, India
[4] Mindanao State Univ, Iligan Inst Technol, Dept Phys, Tibanga Highway, Ilign City 9200, Philippines
[5] North China Elect Power Univ, Coll Energy Dynam & Mech Engn, Beijing, Peoples R China
[6] Cent South Univ, Sch Phys & Elect, Changsha 410083, Peoples R China
[7] Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem, Minist Educ Peoples Republ China, Harbin 150080, Peoples R China
[8] Natl Univ Sci & Technol, Sch Nat Sci, Dept Chem, Islamabad 44000, Pakistan
关键词
Composite; Magnetic material; Magnetic properties; Catalytic properties; METHYLENE-BLUE; P-NITROTOLUENE; ADSORPTION PERFORMANCE; FACILE SYNTHESIS; REMOVAL; EFFICIENT; NANOCOMPOSITE; DEGRADATION;
D O I
10.1016/j.inoche.2022.109422
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
One of the noticeable problem of the environment is deterioration of drinking water quality because of the discharge of industrial wastewater comprising toxic organic molecules. Herein, an eco-friendly graphene oxide assimilated Fe3O4 was synthesized by co-precipitation method for efficient adsorption of 4-nitrotoluene from water. The as-synthesized Fe3O4/GO composite was characterized by XRD, FTIR, SEM, TEM, VSM, EDX and few classical techniques. Characterization results revealed the successful formation of Fe3O4/GO composite. The adsorption results obtained over Fe3O4/GO composite were best fitted to Freundlich isotherm model (R-2 = 0.991) and pseudo-second-order kinetic model (R-2 = 0.990). The thermodynamic parameters suggested the adsorption reaction were favourable, spontaneous and exothermic. Besides, the composite also showed good desorption and recyclability due to its high stable magnetic nature. Moreover, the composite retained equivalent % adsorption capability (> 95.7%) even after several consecutive cycles, verifying its prospective applicability for drinking water cleansing at industrial and domestic level.
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页数:11
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