Probing the thermal stability of μ-oxo triruthenium clusters

被引：2

作者：

Neves da Silva, Camila Fontes ^{[1
]}

de Almeida, Eduardo Tonon ^{[2
]}

Nikolaou, Sofia ^{[3
]}

Pereira Alexiou, Anamaria Dias ^{[3
]}

机构：

[1] Univ Sao Paulo, Inst Quim, Dept Bioquim, LPFI, Sao Paulo, Brazil

[2] Univ Fed Alfenas, LabIQ Inst Quim, Alfenas, MG, Brazil

[3] Univ Sao Paulo, Dept Quim, Lab Atividade Biol & Quim Supramol Compostos Coor, LABiQSC2,Fac Filosofia Ciencias & Letras Ribeirao, Av Bandeirantes 3900, BR-14040901 Ribeirao Preto, SP, Brazil

来源：

POLYHEDRON | 2021年 / 198卷

基金：

巴西圣保罗研究基金会;

关键词：

Ruthenium complexes; Thermal stability; Carbonyl clusters; Nitrosyl clusters; COMPLEXES; RUTHENIUM;

D O I：

10.1016/j.poly.2021.115051

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This work presents for the first time a systematic investigation on the thermal decomposition and thermal stability of ten representative triruthenium clusters of general formula [Ru-3(mu(3)-O)(mu-Ac)(6)(L)(2)L '](n) (Ac = CH3COO and L = N-heterocycles or H2O; L ' = py, Ac, H2O, CO or NO; n = 1+ or 0). Despite the variation of the N-heterocyclic L ligands, the pyridyl, nitrosyl and carbonyl species are quite similar in terms of their thermal decomposition path. The loosely bound solvent molecules are lost first, followed by the loss of the N-heterocyclic ligands, with the final collapse of the metallic core upon acetates oxidation in the range from 270 to 300 degrees C. Their thermal stability depends on the nature of the L and L ' ligands, varying up to 60 degrees depending on the presence of NO, CO or N-heterocyclic ligands. (C) 2021 Elsevier Ltd. All rights reserved.

引用

页数：6

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