Corrosion inhibition of mild steel in acidic solution by leaves and stem extract of Acacia nilotica

被引:7
作者
Mahgoub, Fatma M. [1 ]
Hefnawy, Ahmed M. [1 ]
Abd Alrazzaq, Eman H. [1 ]
机构
[1] Alexandria Univ, Inst Grad Studies & Res, Mat Sci Dept, Alexandria, Egypt
关键词
Adsorption; Acacia nilotica; Corrosion inhibition; Mild steel; Acidic solution; M HCL SOLUTION; HYDROCHLORIC-ACID; CARBON-STEEL; GREEN; DERIVATIVES; ALUMINUM; TEMPERATURE; COPPER;
D O I
10.5004/dwt.2019.24681
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Plant extracts have become vital as an eco-friendly and renewable resource for a wide range of corrosion inhibition applications. In this work, the inhibitive action of water extracts of Vachellia nilotica (VN) leaves and gum arabic (GA) stem of the Acacia nilotica on the corrosion of mild steel was studied using electrochemical measurements. The plant extracts were characterized by Fourier transforms infrared spectroscopy (FTIR), scanning electron microscopy, energy dispersive X-ray spectroscopy and also gas chromatography-mass spectrometry analysis to detect the majority of organic natural compounds in the extract. The adsorption of the inhibitor on mild steel surface was found to follow the Langmuir adsorption isotherm. Surface characterization by FTIR and SEM confirmed the formation of a protective layer on the mild steel surface. The efficiency obtained from the impedance data was around 89% for VN leaves and 86% for GA stem at 25 degrees C. From these results, we conclude that VN leaves and GA stem show promising results as an eco-friendly and mild steel corrosion inhibitors.
引用
收藏
页码:49 / 58
页数:10
相关论文
共 47 条
[1]   Aminopyrimidine derivatives as inhibitors for corrosion of 1018 carbon steel in nitric acid solution [J].
Abdallah, M. ;
Helal, E. A. ;
Fouda, A. S. .
CORROSION SCIENCE, 2006, 48 (07) :1639-1654
[2]   The effects of Aloe vera extract on corrosion and kinetics of corrosion process of zinc in HCl solution [J].
Abiola, Olusegun K. ;
James, A. O. .
CORROSION SCIENCE, 2010, 52 (02) :661-664
[3]   Synthesis and characterization of a novel organic corrosion inhibitor for mild steel in 1 M hydrochloric acid [J].
Ahmed, Mohammed H. Othman ;
Al-Amiery, Ahmed A. ;
Al-Majedy, Yasmin K. ;
Kadhum, Abdul Amir H. ;
Mohamad, Abu Bakar ;
Gaaz, Tayser Sumer .
RESULTS IN PHYSICS, 2018, 8 :728-733
[4]  
Alaneme K., 2016, ALEX ENG J, V55, P1076
[5]  
[Anonymous], INT J ELECTROCHEMICA
[6]   Volatile corrosion inhibitors for ferrous and non-ferrous metals and alloys: A review [J].
Ansari, F. A. ;
Verma, C. ;
Siddiqui, Y. S. ;
Ebenso, E. E. ;
Quraishi, M. A. .
INTERNATIONAL JOURNAL OF CORROSION AND SCALE INHIBITION, 2018, 7 (02) :126-150
[7]   Electrical conducting Xanthan Gum-graft-polyaniline as corrosion inhibitor for aluminum in hydrochloric acid environment [J].
Babaladimath, Gangadhar ;
Badalamoole, Vishalakshi ;
Nandibewoor, S. T. .
MATERIALS CHEMISTRY AND PHYSICS, 2018, 205 :171-179
[8]   Chemically modified natural polysaccharide as green corrosion inhibitor for mild steel in acidic medium [J].
Banerjee, Sitashree ;
Srivastava, Varsha ;
Singh, M. M. .
CORROSION SCIENCE, 2012, 59 :35-41
[9]   Some amino acids as corrosion inhibitors for copper in nitric acid solution [J].
Barouni, K. ;
Bazzi, L. ;
Salghi, R. ;
Mihit, M. ;
Hammouti, B. ;
Albourine, A. ;
El Issami, S. .
MATERIALS LETTERS, 2008, 62 (19) :3325-3327
[10]   The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media [J].
Bentiss, F ;
Traisnel, M ;
Lagrenee, M .
CORROSION SCIENCE, 2000, 42 (01) :127-146