Synthesis and characterization of the epoxy-functionalized quaternary ammonium chloride

被引：9

作者：

Liu, Yingwei ^{[1
]}

Yang, Xiaodeng ^{[1
]}

Li, Yan ^{[1
]}

Chen, Yijian ^{[2
]}

Zhou, Xiangzhu ^{[1
]}

Li, Tianduo ^{[1
]}

机构：

[1] Qilu Univ Technol, Key Lab Fine Chem Shandong Prov, Jinan 250353, Peoples R China

[2] China Univ Petr, Sch Petr Engn, Qingdao 266580, Peoples R China

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2016年 / 498卷

基金：

中国国家自然科学基金;

关键词：

N,N-dimethyl-N-dodecyl-N-(1,2-epoxy propyl) ammonium chloride (DDEAC); Surface activity; Aggregation behavior; Thermodynamical property; Reactivity; IMIDAZOLIUM IONIC LIQUIDS; AGGREGATION BEHAVIOR; ANIONIC SURFACTANTS; ANTIMICROBIAL ACTIVITY; AQUEOUS-SOLUTION; IRON-ORE; CHITOSAN; MICELLIZATION; CONDUCTIVITY; FLUORESCENCE;

D O I：

10.1016/j.colsurfa.2016.03.066

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A kind of surface active epoxy-functionalized quaternary ammonium salt, N,N-dimethyl-N-dodecyl-N-(1,2-epoxy propyl) ammonium chloride (DDEAC), was synthesized. The surface activity and aggregation behavior were investigated by surface tension, dynamic light scattering, conductivity, steady state fluorescence measurements and by molecular dynamics simulations. As a control, the surface properties of dodecyl trimethyl ammonium chloride (DTAC) were also studied. Compared to DTAC, DDEAC showed higher surface activity and more ready aggregation formation as well as larger Ca2+ and Na+ tolerance. The data from molecular dynamics simulations showed that the DDEAC hydrated more easily than DTAC. The conductivity results indicated that the micellization of DDEAC is enthalpy-driven, however that of DTAC is enthalpy-driven only at temperatures higher than 25 degrees C and entropy-driven at temperatures lower than 25 degrees C. The reaction between DDEAC and chitosan implied that DDEAC could endow chitosan both hydrophilicity and hydrophobicity by one step reaction method and expand the application of chitosan. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：248 / 257

页数：10

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