A novel copper-rich open-framework chalcogenide constructed from octahedral Cu4Se6 and icosahedral Cu8Se13 nanoclusters

被引：34
作者：
Yang, Huajun [1 ]
Wang, Le [1 ]
Hu, Dandan [1 ]
Lin, Jian [1 ]
Luo, Li [1 ]
Wang, Hongxiang [1 ]
Wu, Tao [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 22期
基金：
中国国家自然科学基金;
关键词：
INORGANIC MATERIALS; SOLAR-CELL; CLUSTERS; SULFIDE; EFFICIENCY; CHEMISTRY; PROPERTY;
D O I：
10.1039/c6cc00183a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We demonstrated a unique copper-rich open-framework chalcogenide constructed from icosahedral Cu8Se13 and octahedral Cu4Se6 nanoclusters connected to each other through a SnSe3(Se-2) bridging unit. The specific copper-rich composition gives rise to a narrow band gap and photoelectrical responsive properties in the infrared range.
引用
收藏
页码：4140 / 4143
页数：4
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