Recent developments in the asymmetric organocatalytic Morita-Baylis-Hillman reaction

被引：98
作者：
Pellissier, Helene [1 ]
机构：
[1] Aix Marseille Univ, CNRS, Cent Marseille, iSm2, Marseille, France
来源：
TETRAHEDRON | 2017年 / 73卷 / 20期
关键词：
Asymmetric (aza)-Morita-Baylis-Hillman reaction; Organocatalysis; Asymmetric catalysis; Chiral substrates; Allylic substitution reactions; 1,3-Dipolar cycloadditions; N-SULFONATED IMINES; METHYL VINYL KETONE; ALLYLIC-ALLYLIC ALKYLATION; CATALYZED 3+2 ANNULATION; ACTIVATED DOUBLE-BONDS; CHIRAL-PHOSPHINE; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; HILIMAN REACTION; BIFUNCTIONAL ORGANOCATALYSTS;
D O I：
10.1016/j.tet.2017.04.008
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The goal of this review is to collect the recent developments in asymmetric organocatalytic (aza)-Morita-Baylis-Hillman reactions reported since the beginning of 2013. It also includes the asymmetric organocatalysed transformations of racemic (aza)-Morita-Baylis-Hillman adducts, illustrating that they constitute synthetically important synthons in organic chemistry. It is divided into four sections, dealing successively with organocatalytic enantioselective Morita-Baylis-Hillman reactions, organocatalytic enantioselective aza-Morita-Baylis-Hillman reactions, asymmetric (aza)-Morita-Baylis-Hillman reactions of chiral substrates and asymmetric organocatalysed applications of Morita-Baylis-Hillman adducts. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2831 / 2861
页数：31
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