Preparation and coordination complex of the first imine-bridged tetrathiafulvalene-pyridine donor ligand

被引：40
作者：
Chahma, M'hamed
Hassan, Nasser
Alberola, Antonio
Stoeckli-Evans, Helen
Pilkington, Melanie
机构：
[1] Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
[2] Univ Jaume 1, Dept Quim Fis & Analit, Castellon de La Plana 12701, Spain
[3] Inst Microtechnol, CH-2009 Neuchatel, Switzerland
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 10期
关键词：
D O I：
10.1021/ic062257p
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first imine-bridged pyridyltetrathiafulvalene building block (TTF-CH=N-Py, 1) has been synthesized via the Schiff base condensation of formyltetrathiafulvalene and 2-aminopyridine. The preparation, X-ray crystal structure, electrochemical and magnetic characterization of a 1: 1 copper complex [Cu-II(hfac)(2)(TTF-CH=N-Py)] (2) are reported. The crystal structure reveals that the imine N atom participates in chelation to the paramagnetic center, thus making this ligand an attractive precursor for the assembly of pi-d systems.
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页码：3807 / 3809
页数：3
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