New Complexes of Zn(II), Cd(II) and Hg(II) with Ligand Derived from 1-(3,5-diiodo, 2-hydroxy, 4-methyl phenyl), 2-phenyl sulfanyl ethanone

被引：0
|
作者：
Sibiescu, Doina [1 ]
Spatarescu, Irina [1 ]
Rosca, Ioan [1 ]
Cretescu, Igor [1 ]
Secula, Marius Sebastian [1 ]
机构：
[1] Gh Asachi Tech Univ, Fac Chem Engn & Environm Protect, Dept Chem Engn, Iasi 700050, Romania
来源：
REVISTA DE CHIMIE | 2010年 / 61卷 / 02期
关键词：
zinc(II); cadmium(II); mercury(II); 1-(3,5-diiodo, 2-hydroxy, 4-methyl phenyl); 2-phenyl sulfanyl ethanone; precipitating reagent; COORDINATION-COMPOUNDS;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper are presented the conditions to obtain several new complexes through the interaction of Zn(II), Cd(II) and Hg(II) with 1-(3,5-diiodo, 2-hydroxy, 4-methyl phenyl), 2-phenyl sulfanyl ethanone in the molar ratio of 1:2. Also, their characterization was performed by chemical analysis, thermogravimetry, X-ray diffraction and IR absorption spectroscopy. The new complexes crystallize in the monoclinic system with Zn(II), Cd(II) or Hg(II) tetracoordinated as central atoms in tetrahedral structures. The obtaining reactions of these complexes can be used in gravimetric determination of Zn(II), Cd(II) and Hg(II) with an error of 0.25%.
引用
收藏
页码：130 / 134
页数：5
相关论文
共 32 条
  • [1] Syntheses and characterization of Zn(II), Cd(II) and Hg(II) complexes with 5-methyl-1-(2′-pyridyl)-pyrazole-3-carboxamide (MPyPzCA) ligand
    Morsali, A
    Ramazani, A
    JOURNAL OF COORDINATION CHEMISTRY, 2005, 58 (09) : 751 - 758
  • [2] Synthesis and characterization of Cu(II), Co(II), Ni(II), and Zn(II) complexes of a Schiff base derived from 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one and 3-hydroxysalicylaldehyde
    Sönmez, M
    Levent, A
    Sekerci, M
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2003, 33 (10): : 1747 - 1761
  • [3] Zn(II), Cd(II) and Hg(II) complexes with 1-(p-methoxybenzyl)-2-(p-methoxyphenyl)benzimidazole: Syntheses, structures and luminescence
    Manjunatha, M. N.
    Dikundwar, Amol G.
    Nagasundara, K. R.
    POLYHEDRON, 2011, 30 (07) : 1299 - 1304
  • [4] Compounds of Mn(II), Co(II) and Ni(II) with Ligand Derived from Morfolin-4 Carboditioic Acid-2(3,5 Diiod, 4 Methyl 2 Hydroxiphenyl) 2-Oxoethylesther
    Turcuman , Simona
    Sibiescu, Doina
    Rosca, Ioan
    Cretescu, Igor
    Rosca, Catalina Yarodara
    Secula, Marius Sebastian
    REVISTA DE CHIMIE, 2010, 61 (04): : 355 - 359
  • [5] Synthesis, spectral and structural characterization of Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with 2-mercapto-5-methyl-1,3,4-thiadiazole: A Zn(II) complex acting as a new sensitive and selective fluorescent probe for the detection of Hg2+ in H2O-MeOH medium
    Bharati, Pooja
    Bharti, A.
    Bharty, M. K.
    Kashyap, S.
    Singh, U. P.
    Singh, N. K.
    POLYHEDRON, 2013, 63 : 222 - 231
  • [6] Synthesis, Characterization and Thermal Studies of Zn(II), Cd(II) and Hg(II) Complexes of N-Methyl-N-Phenyldithiocarbamate: The Single Crystal Structure of [(C6H5)(CH3)NCS2]4Hg2
    Onwudiwe, Damian C.
    Ajibade, Peter A.
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2011, 12 (03) : 1964 - 1978
  • [7] Mixed-ligand Zn(II) complexes of 1-phenyl-3-methyl-4-forrnylpyrazole-5-one and various aminoheterocycles: Synthesis, structure and photoluminescence properties
    Burlov, Anatolii S.
    Koshchienko, Yurii V.
    Makarova, Nadezhda I.
    Kuz'menko, Tat'yana A.
    Chesnokov, Vasilii V.
    Kiskin, Mikhail A.
    Nikolaevskii, Stanislav A.
    Garnovskii, Dmitrii A.
    Uraev, Ali I.
    Vlasenko, Valerii G.
    Metelitsa, Anatolii V.
    SYNTHETIC METALS, 2016, 220 : 543 - 550
  • [8] Syntheses, characterization of Ni(II)/Zn(II) complexes derived from flexible tricarboxylate ligand and 2,2′-bipyridine and their methyl violet dye photodegradation applications
    Zhong, Wenxu
    Qiang, Hui
    Jiang, Jin
    Wu, Yu
    Padwal, Yogita
    Gosavi, Suresh W.
    Chauhan, Ratna
    Sakiyama, Hiroshi
    Afzal, Mohd
    Alarifi, Abdullah
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1287
  • [9] Kinetic studies of the solvent extraction of UO2(II) and Hg(II) with 4-sebacoylbis(1-phenyl-3-methylpyrazolone-5) in chloroform
    Uzoukwu, BA
    Gloe, K
    Duddeck, H
    RADIOCHIMICA ACTA, 1998, 83 (02) : 69 - 74
  • [10] Synthesis, structural characterization, and biological activities of mononuclear Fe(II), Mn(II), and Ni(II) complexes derived from N-[2-(2-diethylaminoethyliminomethyl)phenyl]-4-methylbenzenesulfonamide
    Vlasenko, Valery G.
    Burlov, Anatolii S.
    Koshchienko, Yurii, V
    Kolodina, Alexandra A.
    Kubrin, Stanislav P.
    Chaltsev, Bogdan, V
    Zubavichus, Yan, V
    Lazarenko, Vladimir A.
    Zubenko, Alexander A.
    Klimenko, Alexander I.
    JOURNAL OF MOLECULAR STRUCTURE, 2022, 1247
1234