Role of intramolecular interactions in Raman spectra of N2 and O2 molecules

被引：34

作者：

Buldakov, MA

Cherepanov, VN ^{[1
]}

Korolev, BV

Matrosov, II

机构：

[1] Tomsk VV Kuibyshev State Univ, Dept Phys, Tomsk 634050, Russia

[2] Russian Acad Sci, SB, Inst Opt Monitoring, Lab Ecol Instrument Making, Tomsk 634055, Russia

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2003年 / 217卷 / 01期

关键词：

vibration-rotation interactions; vibration anharmonicities; polarizability matrix elenients Raman spectroscopy; nitrogen; oxygen;

D O I：

10.1016/S0022-2852(02)00012-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The effect of vibration-rotation interactions and anharmonicities on the polarizabilities matrix elements, Raman scattering cross-sections, and depolarization degrees of N-2 and O-2 molecules for vibrational transitions v --> v, v + 1, v + 2, v + 3 have been investigated. (C) 2002 Elsevier Science (USA). All rights reserved.

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页码：1 / 8

页数：8

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