Surface modification of epoxy resin by polyether-polydimethylsiloxanes-polyether triblock copolymers

被引:24
作者
Huang, W [1 ]
Yao, Y [1 ]
Huang, Y [1 ]
Yu, YZ [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
关键词
surface modification; epoxy resin; static friction coefficient;
D O I
10.1016/S0032-3861(00)00393-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In order to reduce static friction coefficient (mu (s)), polyether-polydimethylsiloxane-polyether triblock copolymers (PER-PDMS-PER) were incorporated into epoxy resins as surface modifiers. It was found that longer PDMS segments in PER-PDMS-PER and higher modifier contents led to lower mu (s) of modified epoxy resins upon stainless steel. The mu (s) of silicone rubber- and PTFE-side surfaces were evidently lower than that of stainless steel-side surface. ESCA investigations indicated that a longer PDMS block in modifier resulted in a flatter PDMS gradient at surface and the degree of PDMS accumulation on PTFE- and silicone rubber-side surfaces were much higher than that on stainless steel-side surface. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1763 / 1766
页数:4
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