Highly efficient dynamic kinetic resolution of secondary aromatic alcohols with low-cost and easily available acid resins as racemization catalysts

被引：17

作者：

Cheng, Yongmei ^{[1
]}

Xu, Gang ^{[1
]}

Wu, Jianping ^{[1
]}

Zhang, Chensheng ^{[1
]}

Yang, Lirong ^{[1
]}

机构：

[1] Zhejiang Univ, Inst Bioengn, Dept Biol & Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 17期

基金：

中国国家自然科学基金;

关键词：

ENZYMATIC RESOLUTION; RUTHENIUM;

D O I：

10.1016/j.tetlet.2010.02.152

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and efficient dynamic kinetic resolution (DKR) process of secondary aromatic alcohols was developed with acid resins as racemization catalysts. Acid resin CD8604 was shown to have excellent racemization activity and good biocompatibility. When employing CD8604 and complex acyl donors as racemization catalyst and acyl donor, respectively, enantiomerically pure aromatic acetate was obtained with excellent yield and ee values through the DKR process. It is noteworthy that the system could be reused more than 10 times with little loss of yield and ee value. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2366 / 2369

页数：4

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