Catalyst-controlled divergent transformations of N-sulfonyl-1,2,3-triazoles into isoquinolin-3-ones and 2-aminoindanones

被引：1

作者：

Lee, Kyu Ree ^{[1
]}

Jung, Da Jung ^{[1
]}

Ahn, Subin ^{[1
]}

Kim, Ji Won ^{[1
]}

Lee, Sang-gi ^{[1
]}

机构：

[1] Ewha Womans Univ, Dept Chem & Nanosci, Seoul 03760, South Korea

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 23期

基金：

新加坡国家研究基金会;

关键词：

N-SULFONYL 1,2,3-TRIAZOLES; NATURAL-PRODUCTS; REARRANGEMENT; LIGAND; BOND; HETEROCYCLES; CARBENES; UTILITY;

D O I：

10.1039/d1ob00708d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel catalyst-controlled divergent intramolecular reactions of N-sulfonyl-1,2,3-triazoles with tethered-allylic alcohol have been developed. In the presence of the Pd(0) catalyst alone, 1-vinylated 1,4-dihydroisoquinolin-3-ones were formed, whereas 3-vinylated 2-aminoindanones were accessed under tandem, one-pot, Rh(ii)/Pd(0) dual catalytic conditions. Based on deuterium-labelling experiments and isolation of the intermediate, a plausible reaction mechanism has been proposed.

引用

页码：5093 / 5097

页数：5

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