Palladium-catalysed amination of 1,8-and 1,5-dichloroanthracenes and 1,8-and 1,5-dichloroanthraquinones

被引：0
作者：
Beletskaya, IP [1 ]
Bessmertnykh, AG
Averin, AD
Denat, F
Guilard, R
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
[2] Univ Bourgogne, Fac Sci Gabriel, Lab Ingn Mol Separat & Applicat Gaz, UMR 5633, F-21100 Dijon, France
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 2005卷 / 02期
关键词：
amines; aromatic substitution; homogeneous catalysis; macrocycles; palladium;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Diamino derivatives of anthracene and anthraquinone have been synthesised by palladium-catalysed coupling of 1,8-dichloroanthracene and 1,8-dichloroanthraquinone with a wide range of aliphatic and aromatic primary and secondary amines. The use of polyamines gave rise to a large number of new nitrogen- and oxygen-containing macrocycles incorpo-rating anthracene or anthraquinone moieties. The method has also been employed for the preparation of bismacrocycles in which two cyclam or azacrown units are linked together by an anthracene bridge through C(sp(2))-N bonds. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
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页码：281 / 305
页数：25
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