Kinetics of thermal degradation in non-isothermal conditions of some phosphorus-containing polyesters and polyesterimides

被引：70

作者：

Hamciuc, Corneliu

Vlad-Bubulac, Tachita

Petreus, Oana

Lisa, Gabriela

机构：

[1] Inst Macromol Chem Petru Poni, Iasi 700487, Romania

[2] Tech Univ Gh Asachi, Fac Ind Chem, Iasi 700050, Romania

来源：

EUROPEAN POLYMER JOURNAL | 2007年 / 43卷 / 03期

关键词：

thermal stability; thermal degradation kinetics; phosphorus-containing polymers; flame retardant;

D O I：

10.1016/j.eurpolymj.2006.12.018

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The thermal decomposition behavior of some phosphorus-containing polyesters and a polyesterimide was studied using thermogravimetric analysis in air at several heating rates between 5 degrees C/min and 20 degrees C/min. The results of this study, realized for polymers with phosphorus linkage as pendant group, were compared with the behavior of some polymers having the same backbone structure, with phosphorus in the main chain, respectively, without phosphorus. The kinetic processing of data was carried out using the Coats-Redfern, Reich-Levi, Flynn-Wall-Ozawa and Kissinger methods. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：980 / 988

页数：9

共 29 条

[1] Thermotropic liquid-crystalline polyesters of 4,4′-biphenol and phenyl-substituted 4,4′-biphenols with 4,4′-oxybisbenzoic acid [J].

Bhowmik, PK ;

Han, H ;

Cebe, JJ ;

Burchett, RA .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (01) :141-155

[2]

Chang SJ, 1999, J APPL POLYM SCI, V72, P109, DOI 10.1002/(SICI)1097-4628(19990404)72:1<109::AID-APP12>3.0.CO

[3]

2-Q

[4] KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA [J].

COATS, AW ;

REDFERN, JP .

NATURE, 1964, 201 (491) :68-&

[5] LIQUID-CRYSTALLINE AROMATIC POLYESTERS [J].

ECONOMY, J .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1984, A21 (13-1) :1705-1724

[6] A QUICK DIRECT METHOD FOR DETERMINATION OF ACTIVATION ENERGY FROM THERMOGRAVIMETRIC DATA [J].

FLYNN, JH ;

WALL, LA .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1966, 4 (5PB) :323-&

[7] New phosphorus-containing copolyesters [J].

Hamciuc, Corneliu ;

Vlad-Bubulac, Tachita ;

Sava, Ion ;

Petreus, Oana .

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2006, 43 (09) :1355-1364

[8] Novel phosphorous -: Containing aromatic polyethers -: Synthesis and characterization [J].

Hoffmann, T ;

Pospiech, D ;

Häussler, L ;

Komber, H ;

Voigt, D ;

Harnisch, C ;

Kollann, C ;

Ciesielski, M ;

Döring, M ;

Perez-Graterol, R ;

Sandler, J ;

Altstädr, V .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2005, 206 (04) :423-431

[9] REACTION KINETICS IN DIFFERENTIAL THERMAL ANALYSIS [J].

KISSINGER, HE .

ANALYTICAL CHEMISTRY, 1957, 29 (11) :1702-1706

[10]

Kricheldorf HR, 1999, ADV POLYM SCI, V141, P83

← 1 2 3 →