New mimic of zeolite: heterometallic organic host framework accommodating inorganic cations

被引：43

作者：

Chen, Yu-Biao ^{[1
]}

Kang, Yao ^{[1
]}

Zhang, Jian ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 18期

关键词：

COORDINATION POLYMERS; IONOTHERMAL SYNTHESIS; METAL; ZMOFS; STORAGE; DESIGN;

D O I：

10.1039/b927101e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Presented here is a heterometallic organic framework [Na-2(H2O)(10)](n)[CuZn4(mu(3)-OH)(4)(btec)(2)](n)center dot 2nH(2)O (1, btec = 1,2,4,5-benzenetetracarboxylate) that incorporates mixed Cu2+-Zn2+ oxide chains and accommodates Na+ cations as extraframework guest species; such a building mode is comparable to that of aluminosilicate zeolites where the porous framework combines two kinds of structural building units (such as [SiO4] and [AlO4]) and one kind of inorganic-templating cation.

引用

页码：3182 / 3184

页数：3

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