A simple mild hydrothermal route for the synthesis of nickel phosphide powders

被引：35

作者：

Liu, Zongyi ^{[1
]}

Huang, Xiang ^{[1
]}

Zhu, Zhibin ^{[1
]}

Dai, Jinhui ^{[1
]}

机构：

[1] Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2010年 / 36卷 / 03期

关键词：

Hydrothermal; Nickel phosphides; Red phosphorous; SOLVOTHERMAL ROUTE; METAL; DEPOSITION; CONVENIENT; TUNGSTEN; NI2P;

D O I：

10.1016/j.ceramint.2009.12.015

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Nickel phosphide was synthesized via a hydrothermal reaction between nickel chloride (NiCl2 center dot 6H(2)O) and red phosphor (P) in water at 200 degrees C. Phase constitution, morphology and composition were determined by XRD, SEM and EDS, respectively. The effect on the final products of experimental conditions such as the molar ratio of red phosphor to nickel chloride and reaction time were discussed, as well as the formation mechanism of nickel phosphides. (C) 2009 Elsevier Ltd and Techna Group Sri. All rights reserved.

引用

页码：1155 / 1158

页数：4

共 12 条

[1]

Aronsson B., 1965, BORIDES SILICIDES PH

[2] PREPARATION OF PHOSPHIDES IN THE COMBUSTION REGIME [J].

CHERNOGORENKO, VB ;

MUCHNIK, SV ;

LYNCHAK, KA ;

KLIMAK, ZA ;

IVANCHENKO, VG .

MATERIALS RESEARCH BULLETIN, 1981, 16 (01) :1-6

[3] MAGNETIC AND STRUCTURAL-PROPERTIES OF TRANSITION-METAL SUBSTITUTED MNP .3. MN1-TFETP (0.00 LESS-THAN-OR-EQUAL-TO T LESS-THAN-OR-EQUAL-TO 0.30) [J].

FJELLVAG, H ;

KJEKSHUS, A ;

ANDRESEN, AF .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1984, 38 (09) :711-717

[4] VAPORIZATION BEHAVIOR + PHOSPHORUS DECOMPOSITION PRESSURES OF TUNGSTEN MONOPHOSPHIDE [J].

GINGERICH, KA .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (04) :768-&

[5] PRECURSOR FOR THE LOW-TEMPERATURE DEPOSITION OF TITANIUM PHOSPHIDE FILMS [J].

LEWKEBANDARA, TS ;

PROSCIA, JW ;

WINTER, CH .

CHEMISTRY OF MATERIALS, 1995, 7 (06) :1053-1054

[6] Molybdenum phosphide: A novel catalyst for hydrodenitrogenation [J].

Li, W ;

Dhandapani, B ;

Oyama, ST .

CHEMISTRY LETTERS, 1998, (03) :207-208

[7] CHEMICAL VAPOR-DEPOSITION OF NICKEL PHOSPHIDE NI2P [J].

MOTOJIMA, S ;

HAGURI, K ;

TAKAHASHI, Y ;

SUGIYAMA, K .

JOURNAL OF THE LESS-COMMON METALS, 1979, 64 (01) :101-106

[8] CONVENIENT SYNTHESIS OF LANTHANIDE AND MIXED LANTHANIDE PHOSPHIDES BY SOLID-STATE ROUTES INVOLVING SODIUM PHOSPHIDE [J].

ROWLEY, AT ;

PARKIN, IP .

JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (07) :689-692

[9] NEW METAL-RICH PHOSPHIDES OF NIOBIUM TANTALUM AND TUNGSTEN [J].

RUNDQVIST, S .

NATURE, 1966, 211 (5051) :847-+

[10] AN X-RAY INVESTIGATION OF TRANSITION METAL PHOSPHIDES [J].

SCHONBERG, N .

ACTA CHEMICA SCANDINAVICA, 1954, 8 (02) :226-239

← 1 2 →