Polyion complex stabilized palladium nanoparticles for Suzuki and Heck reaction in water

被引:34
作者
Ohtaka, Atsushi [1 ]
Tamaki, Yuji [1 ]
Igawa, Yuta [1 ]
Egami, Koji [1 ]
Shimomura, Osamu [1 ]
Nomura, Ryoki [1 ,2 ]
机构
[1] Osaka Inst Technol, Fac Engn, Dept Appl Chem, Asahi Ku, Osaka 5358585, Japan
[2] Osaka Inst Technol, Nanomat & Microdevices Res Ctr, Asahi Ku, Osaka 5358585, Japan
关键词
Palladium nanoparticles; Polyion complex; Coupling reaction; Water; CATALYZED REACTIONS; COUPLING REACTIONS; BOND FORMATIONS; EFFICIENT; OLEFINS;
D O I
10.1016/j.tet.2010.05.076
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Palladium nanoparticles stabilized by a polyion complex composed of poly{4-chloromethylstyrene-co-(4-vinylbenzyl) tributylammonium chloride} and poly(acrylic acid) were easily recovered by filtration after pH treatment. The polyion complex stabilized palladium nanoparticles have high catalytic activity for the Suzuki and Heck reactions in water. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5642 / 5646
页数:5
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