Pd/C: A recyclable catalyst for cyanation of aryl bromides

被引：60

作者：

Zhu, Yi-Zhong ^{[1
]}

Cai, Chun ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Chem Engn Coll, Nanjing 210094, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 2007卷 / 15期

关键词：

cyanation; heterogeneous catalysis; potassium hexacyanoferrate(II); palladium; aryl cyanides;

D O I：

10.1002/ejoc.200700098

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl cyanides have been prepared from the corresponding aryl bromides with potassium hexacyanoferrate(II) using Pd/C as a catalyst. It is shown that the addition of Bu3N is the key factor in obtaining the corresponding aryl cyanides. Furthermore, the catalyst can be recycled by filtration and washing sequences, making the method also attractive for industrial applications. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).

引用

页码：2401 / 2404

页数：4

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