DDQ-Promoted Allylic C-H Phosphorylation of 1,3-Diarylpropenes

被引：21

作者：

Chen, Qian ^{[1
,2
]}

Wen, Chunxiao ^{[1
]}

Wang, Xiaofeng ^{[1
]}

Yu, Guodian ^{[1
]}

Ou, Yingcong ^{[1
]}

Huo, Yanping ^{[1
]}

Zhang, Kun ^{[1
]}

机构：

[1] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China

[2] South China Univ Technol, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 18期

关键词：

phosphorylation; C-H functionalization; DDQ; cross-dehydrogenative coupling; allylphosphonates; DEHYDROGENATIVE-COUPLING REACTIONS; SECONDARY PHOSPHINE OXIDES; MICHAELIS-ARBUZOV; HIGHLY EFFICIENT; METAL-FREE; CROSS; BONDS; COPPER; ARYL; FUNCTIONALIZATION;

D O I：

10.1002/adsc.201800804

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient allylic C-H phosphorylation has been achieved through the DDQ-promoted cross-dehydrogenative coupling of 1,3-diarylpropenes with P(O)H compounds at room temperature. This method provides a convenient route to allylphosphonates in up to 97% yield with good functional group compatibility.

引用

页码：3590 / 3594

页数：5

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