Cobalt-Catalyzed Hydroformylation under Mild Conditions in the Presence of Phosphine Oxides

被引：38

作者：

Delolo, Fabio G. ^{[1
,2
]}

Yang, Ji ^{[2
]}

Neumann, Helfried ^{[2
]}

dos Santos, Eduardo N. ^{[1
]}

Gusevskaya, Elena, V ^{[1
]}

Beller, Matthias ^{[2
]}

机构：

[1] Univ Fed Minas Gerais, Dept Quim, BR-31270901 Belo Horizonte, MG, Brazil

[2] Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2021年 / 9卷 / 14期

关键词：

carbonylation; oxo process; green solvents; catalysis promoter; bulky olefins; RHODIUM(I) COMPLEXES; LIGANDS; OLEFINS; OCTENES;

D O I：

10.1021/acssuschemeng.1c00205

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of phosphine oxides, specifically triphenylphosphine oxide (P14), the cobalt-catalyzed hydroformylation of olefins takes place under mild conditions compared to traditional processes. It is shown that the addition of P14 dramatically improves the preactivation of the classic cobalt precatalyst, thus saving time and energy. In addition, we show that anisole, a solvent with a high sustainability rank, can be used advantageously in such processes.

引用

页码：5148 / 5154

页数：7

共 41 条

[1] PHOSPHINE VS PHOSPHINE OXIDE LIGANDS IN HYDROFORMYLATION REACTIONS [J].

ABUGNIM, C ;

AMER, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) :115-117

[2] Phosphine oxides as ligands in the hydroformylation reaction [J].

AbuGnim, C ;

Amer, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 516 (1-2) :235-243

[3] Updating and further expanding GSK's solvent sustainability guide [J].

Alder, Catherine M. ;

Hayler, John D. ;

Henderson, Richard K. ;

Redman, Aniko M. ;

Shukla, Lena ;

Shuster, Leanna E. ;

Sneddon, Helen F. .

GREEN CHEMISTRY, 2016, 18 (13) :3879-3890

[4] HYDROFORMYLATION OF SOME FUNCTIONALIZED OLEFINS CATALYZED BY RHODIUM(I) COMPLEXES WITH PYDIPHOS AND ITS P-OXIDE [J].

BASOLI, C ;

BOTTEGHI, C ;

CABRAS, MA ;

CHELUCCI, G ;

MARCHETTI, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 488 (1-2) :C20-C22

[5]

Behr A., 2012, APPL HOMOGENEOUCAT, V1st

[6] PROGRESS IN HYDROFORMYLATION AND CARBONYLATION [J].

BELLER, M ;

CORNILS, B ;

FROHNING, CD ;

KOHLPAINTNER, CW .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 104 (01) :17-85

[7]

Borner A., 2016, HYDROFORMYLATION FUN

[8] Recent Developments in the Scope, Practicality, and Mechanistic Understanding of Enantioselective Hydroformylation [J].

Brezny, Anna C. ;

Landis, Clark R. .

ACCOUNTS OF CHEMICAL RESEARCH, 2018, 51 (09) :2344-2354

[9]

CENTINI G, 1967, J ORGANOMET CHEM, V8, P149

[10] Hydroformylation of alkenes employing rhodium(I) complexes and a phosphine oxide ligand [J].

Clark, HJ ;

Wang, RP ;

Alper, H .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (17) :6224-6225

← 1 2 3 4 5 →