Palladium-catalyzed oxidative cyclization of 1,4- and 1,5-diols in 1,2-dichloroethane

被引：25

作者：

Ait-Mohand, S ^{[1
]}

Muzart, J ^{[1
]}

机构：

[1] Univ Reims Champagne Ardenne, CNRS, Unite Mixte Rech React Select & Applicat, F-51687 Reims 2, France

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 129卷 / 2-3期

关键词：

palladium-catalysis; lactonisation; 1,2-dichloroethane; oxidation; 1; n-diols;

D O I：

10.1016/S1381-1169(97)00140-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

beta- and delta-lactones have been obtained from diols in 1,2-dichloroethane containing sodium carbonate and catalytic amounts of both palladium chloride and Adogen 464. In one case, the reaction stopped at the level of the lactol; a dealkoxypalladation is thus suggested. (C) 1998 Elsevier Science B.V.

引用

页码：135 / 139

页数：5

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