The synthesis of C2-symmetric and axially chiral compounds for recognition and catalysis

被引：17

作者：

Clews, J ^{[1
]}

Curtis, ADM ^{[1
]}

Malkin, H ^{[1
]}

机构：

[1] Univ Keele, Sch Chem & Phys, Lennard Jones Labs, Keele ST5 5BG, Staffs, England

来源：

TETRAHEDRON | 2000年 / 56卷 / 44期

关键词：

guanidines; amidines; molecular recognition; axial chirality;

D O I：

10.1016/S0040-4020(00)00803-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Axially chiral amidines and guanidines. some possessing C-2-symmetry, have been targeted as potential chiral catalysts for reactions of alpha,beta -unsaturated carboxylic acids or esters. The key step in each synthesis required the coupling of two sterically demanding aromatic compounds to form atropisomeric biaryl species. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：8735 / 8746

页数：12

共 50 条

[31] Design and Synthesis of C4-Symmetric Axially Chiral β-Aryl Porphyrins and Application for Supporting Ir(III)-Catalyzed Enantioselective C-H Alkylation [J].

Yuan, Shanshan ;

Sun, Jun-Chao ;

Zhao, Xiao-Ming ;

Zhu, Jieping ;

Zheng, Sheng-Cai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (28)

[32] A palladium complex containing a new C2-symmetric bidentate non-racemic oxalamidine ligand:: synthesis and catalytic properties [J].

Dupont, J ;

Ebeling, G ;

Delgado, MR ;

Consorti, CS ;

Burrow, R ;

Farrar, DH ;

Lough, AJ .

INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (09) :471-474

[33] Towards Atropoenantiopure N-C Axially Chiral Compounds via Stereoselective C-N Bond Formation [J].

Frey, Johanna ;

Choppin, Sabine ;

Colobert, Francoise ;

Wencel-Delord, Joanna .

CHIMIA, 2020, 74 (11) :883-889

[34] Ir-catalyzed Sequential Asymmetric Allylic Substitution/Olefin Isomerization for the Synthesis of Axially Chiral Compounds [J].

Zhao, Qing-Ru ;

Jiang, Ru ;

You, Shu-Li .

ACTA CHIMICA SINICA, 2021, 79 (09) :1107-1112

[35] Synthesis of rigid and C2-symmetric 18-crown-6 type macrocycles bearing diamide-diester groups: enantiomeric recognition for α-(1-naphthyl) ethylammonium perchlorate salts [J].

Baris, Deniz ;

Seker, Sevil ;

Hosgoren, Halil ;

Togrul, Mahmut .

TETRAHEDRON-ASYMMETRY, 2010, 21 (15) :1893-1899

[36] Enantioselective C-H Borylation for the Synthesis of Axially Chiral N-Aryl Phthalimides [J].

Zhao, Hongliang ;

Chen, Lili ;

Xia, Chungu ;

Xu, Senmiao .

ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 12 (02)

[37] Synthesis of 2,2′-bipyridines with axially chiral 1,1′-binaphthalene units [J].

Hodacová, J ;

Stibor, I .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2000, 65 (01) :83-98

[38] Novel C1-symmetric chiral crown ethers bearing rosin acids groups: synthesis and enantiomeric recognition for ammonium salts [J].

Liu, Lu-zhi ;

He, Chun-huan ;

Yang, Lin ;

Huang, Yan ;

Wu, Qiang ;

Duan, Wen-gui ;

Wang, Heng-shan ;

Pan, Ying-ming .

TETRAHEDRON, 2014, 70 (50) :9545-9553

[39] Organocatalytic Atroposelective Intramolecular [4+2] Cycloaddition: Synthesis of Axially Chiral Heterobiaryls [J].

Liu, Yidong ;

Wu, Xiaoyan ;

Li, Shan ;

Xue, Lu ;

Shan, Chunhui ;

Zhao, Zhengxing ;

Yan, Hailong .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (22) :6491-6495

[40] C2-Symmetric 1,2-di(fluorenylidene)cyclobutanes : syntheses, structures, rearrangements and reactivity [J].

Milosevic, Sandra ;

Mueller-Bunz, Helge ;

Ortin, Yannick ;

Schreiber, Dominique ;

Phillips, Andrew D. ;

McGlinchey, Michael J. .

TETRAHEDRON, 2015, 71 (31) :5045-5054

← 1 2 3 4 5 →