Catalytic Response and Stability of Nickel/Alumina for the Hydrogenation of 5-Hydroxymethylfurfural in Water

被引：83

作者：

Perret, Noemie ^{[1
]}

Grigoropoulos, Alexios ^{[1
]}

Zanella, Marco ^{[1
]}

Manning, Troy D. ^{[1
]}

Claridge, John B. ^{[1
]}

Rosseinsky, Matthew J. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Crown St, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMSUSCHEM | 2016年 / 9卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

5-hydroxymethylfurfural; hydrogenation; layered compounds; nickel; water; LAYERED DOUBLE HYDROXIDES; SYNTHETIC HYDROTALCITES; PHYSICOCHEMICAL PROPERTIES; RING REARRANGEMENT; FURAN-DERIVATIVES; CONVERSION; BIOMASS; NI; CHEMICALS; ROUTES;

D O I：

10.1002/cssc.201501225

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic response of Ni on Al2O3 obtained from Ni-Al layered double hydroxides was studied for the liquid-phase hydrogenation of hydroxymethyl furfural to tetrahydrofuran-2,5-diyldimethanol (THFDM) in water. The successive calcination and reduction of the precursors caused the removal of interlayer hydroxyl and carbonate groups and the reduction of Ni2+ to Ni-0. Four reduced mixed oxide catalysts were obtained, consisting of different amount of Ni metal contents (47-68wt%) on an Al-rich amorphous component. The catalytic activity was linked to Ni content whereas selectivity was mainly affected by reaction temperature. THFDM was formed in a stepwise manner at low temperature (353K) whereas 3-hydroxymethyl cyclopentanone was generated at higher temperature. Coke formation caused deactivation; however, the catalytic activity can be regenerated using heat treatment. The results establish Ni on Al2O3 as a promising catalyst for the production of THFDM in water.

引用

页码：521 / 531

页数：11

共 65 条

[1] Activated takovite catalysts for partial hydrogenation of ethyne, propyne, and propadiene [J].

Abello, Sonia ;

Verboekend, Danny ;

Bridier, Blaise ;

Perez-Ramirez, Javier .

JOURNAL OF CATALYSIS, 2008, 259 (01) :85-95

[2] The selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using heterogeneous catalysts [J].

Alamillo, Ricardo ;

Tucker, Mark ;

Chia, Mei ;

Pagan-Torres, Yomaira ;

Dumesic, James .

GREEN CHEMISTRY, 2012, 14 (05) :1413-1419

[3] Heterogeneous Catalyst Deactivation and Regeneration: A Review [J].

Argyle, Morris D. ;

Bartholomew, Calvin H. .

CATALYSTS, 2015, 5 (01) :145-269

[4]

Atkinson A., 1989, GRAIN BOUNDARY DIFFU, P280

[5] Etherification and reductive etherification of 5-(hydroxymethyl)furfural: 5-(alkoxymethyl)furfurals and 2,5-bis(alkoxymethyl)furans as potential bio-diesel candidates [J].

Balakrishnan, Madhesan ;

Sacia, Eric R. ;

Bell, Alexis T. .

GREEN CHEMISTRY, 2012, 14 (06) :1626-1634

[6] VOIGT-FUNCTION MODELING IN FOURIER-ANALYSIS OF SIZE-BROADENED AND STRAIN-BROADENED X-RAY-DIFFRACTION PEAKS [J].

BALZAR, D ;

LEDBETTER, H .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 1) :97-103

[7] Size-strain line-broadening analysis of the ceria round-robin sample [J].

Balzar, D ;

Audebrand, N ;

Daymond, MR ;

Fitch, A ;

Hewat, A ;

Langford, JI ;

Le Bail, A ;

Louër, D ;

Masson, O ;

McCowan, CN ;

Popa, NC ;

Stephens, PW ;

Toby, BH .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2004, 37 :911-924

[8] Hydrotalcite-type precursors of active catalysts for hydrogen production [J].

Basile, F. ;

Benito, P. ;

Fornasari, G. ;

Vaccari, A. .

APPLIED CLAY SCIENCE, 2010, 48 (1-2) :250-259

[9]

Basu P., 2009, INTEGRATED APPROACH, P21

[10] Conversion of Biomass into Chemicals over Metal Catalysts [J].

Besson, Michele ;

Gallezot, Pierre ;

Pinel, Catherine .

CHEMICAL REVIEWS, 2014, 114 (03) :1827-1870

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