Heavy-metal pi complexes .12. A monomeric bis(arene)lead(II) complex with a plumbocene-like bent sandwich structural unit - Structure of [Pb(1,2-C6H4Me2)(2)(AlCl4)(2)]

被引：24
作者：
Frank, W
Wittmer, FG
机构：
[1] Fachbereich Chemie, Universität Kaiserslautern, D-67653 Kaiserslautern
来源：
CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 12期
关键词：
lead; tetrachloroaluminate; arenes; omicron-xylene; bis(arene) complexes;
D O I：
10.1002/cber.19971301204
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bis(o-xylene)lead(II) bis (tetrachloroaluminate), obtained from lead(II) chloride and aluminium trichloride in o-xylene, has been shown by X-ray crystallography to be a mononuclear lead complex with point group symmetry C-2. The two aromatic ligands are arranged similarly to those in monomeric plumbocene. The coordination sphere is completed by two bidentate AlCl4 ions. The lead center uses about a quarter of its bonding capability for each of the four ligands.
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页码：1731 / 1732
页数：2
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