Structural and magnetic properties of a self-assembled spheroidal triakonta-hexanuclear Cu36 cluster

被引:53
作者
Abedin, TSM [1 ]
Thompson, LK [1 ]
Miller, DO [1 ]
Krupicka, E [1 ]
机构
[1] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada
关键词
D O I
10.1039/b211401c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An extended tritopic picolinic dihydrazide ligand with terminal oxime groups (dpocco) undergoes spontaneous self-assembly in the presence of copper acetate to produce a unique Cu-36 cluster exhibiting intramolecular anti-ferromagnetic exchange.
引用
收藏
页码:708 / 709
页数:2
相关论文
共 15 条
  • [1] Multicomponent self-assembly: Preferential generation of a rectangular [2x3]G grid by mixed-ligand recognition
    Baxter, PNW
    Lehn, JM
    Kneisel, BO
    Fenske, D
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (18): : 1978 - 1981
  • [2] 1ST EXAMPLE OF A DISCRETE COPPER(III, II) MIXED-VALENCE COMPLEX - THE TRIANGULAR CUIIICUII2O CORE CIRCUMSCRIBED BY OXIME LIGANDS
    DATTA, D
    CHAKRAVORTY, A
    [J]. INORGANIC CHEMISTRY, 1983, 22 (11) : 1611 - 1613
  • [3] Garcia AM, 1999, CHEM-EUR J, V5, P1803, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1803::AID-CHEM1803>3.0.CO
  • [4] 2-M
  • [5] Towards nanostructured arrays of single molecule magnets: : new Fe19 oxyhydroxide clusters displaying high ground state spins and hysteresis
    Goodwin, JC
    Sessoli, R
    Gatteschi, D
    Wernsdorfer, W
    Powell, AK
    Heath, SL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (12): : 1835 - 1840
  • [6] Tetranuclear copper(II) and nickel(II) cluster complexes derived by self-assembly from a series of tetradentate diazine ligands: Structural and magnetic studies
    Matthews, CJ
    Avery, K
    Xu, ZQ
    Thompson, LK
    Zhao, L
    Miller, DO
    Biradha, K
    Poirier, K
    Zaworotko, MJ
    Wilson, C
    Goeta, AE
    Howard, JAK
    [J]. INORGANIC CHEMISTRY, 1999, 38 (23) : 5266 - 5276
  • [7] Strategies for producing cluster-based magnetic arrays
    Schmitt, W
    Murugesu, M
    Goodwin, JC
    Hill, JP
    Mandel, A
    Bhalla, R
    Anson, CE
    Heath, SL
    Powell, AK
    [J]. POLYHEDRON, 2001, 20 (11-14) : 1687 - 1697
  • [8] Synthesis, structure, and magnetism of a series of self-assembled polynuclear Mn(II), Co(II), and Cu(II) cluster complexes
    Thompson, LK
    Matthews, CJ
    Zhao, L
    Xu, ZQ
    Miller, DO
    Wilson, C
    Leech, MA
    Howard, JAK
    Heath, SL
    Whittaker, AG
    Winpenny, REP
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2001, 159 (02) : 308 - 320
  • [9] Structural and magnetic properties of dicopper(II) complexes of polydentate diazine ligands
    Thompson, LK
    Xu, ZQ
    Goeta, AE
    Howard, JAK
    Clase, HJ
    Miller, DO
    [J]. INORGANIC CHEMISTRY, 1998, 37 (13) : 3217 - 3229
  • [10] Serendipitous assembly of polynuclear cage compounds
    Winpenny, REP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (01): : 1 - 10