Conjugated polyrotaxanes containing coordinating units: reversible copper(I) metallation-demetallation using lithium as intermediate scaffolding

被引：53
作者：
Vidal, PL
Billon, M
Divisia-Blohorn, B
Bidan, G
Kern, JM
Sauvage, JP
机构：
[1] Univ Grenoble 1, CEA, CNRS, UMR 585, F-38054 Grenoble 9, France
[2] Univ Strasbourg 1, Inst Le Bel, Lab Chim Organominerale, UMR 7513, F-67000 Strasbourg, France
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 05期
关键词：
D O I：
10.1039/a708662h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new polyrotaxane containing a conjugated backbone has been synthesized via a copper(I) template and electropolymerisation; after decomplexation of Cu-I, remetallation is only possible if lithium is present during copper removal, as labile scaffolding able to prevent collapse of the free coordination sites and of the organic matrix.
引用
收藏
页码：629 / 630
页数：2
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