Calculations of the energy accommodation coefficient for gas-surface interactions

被引:12
作者
Fan, Guoqing [1 ]
Manson, J. R. [1 ,2 ]
机构
[1] Clemson Univ, Dept Phys & Astron, Clemson, SC 29634 USA
[2] Donostia Int Phys Ctr, San Sebastian 20018, Spain
关键词
Accommodation; Gas-surface interactions; Surface energy transfer; CLEAN TUNGSTEN SURFACES; SOLID-SURFACES; ATOMS; SCATTERING; EXCHANGE; HELIUM;
D O I
10.1016/j.chemphys.2009.12.018
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Calculations are carried out for the energy accommodation coefficient at a gas-surface interface using a recently developed classical mechanical theory of atom-surface collisions that includes both direct scattering and trapping-desorption processes in the physisorption well of the interaction potential. Full three-dimensional calculations are compared with the available data for the accommodation of rare gases at a tungsten surface and reasonable agreement is found for the heavier gases for which classical physics is expected to be valid at all measured temperatures. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:175 / 179
页数:5
相关论文
共 27 条
[21]  
Maxwell J.C., 1879, Philosophical Transactions of the Royal Society, V170, P251
[22]   MULTIPHONON ENERGY-TRANSFER IN ATOM SURFACE SCATTERING [J].
MEYER, HD ;
LEVINE, RD .
CHEMICAL PHYSICS, 1984, 85 (02) :189-200
[23]   Calculations of the energy accommodation coefficient using classical scattering theory [J].
Muis, A ;
Manson, JR .
SURFACE SCIENCE, 2001, 486 (1-2) :82-94
[25]  
Saxena S. C., 1989, CINDAS Data Series on Material Properties Group II, Properties of Special Materials, VII-1
[26]  
Thomas L. B., 1967, RAREFIED GAS DYN, P155
[27]  
Thomas L.B., 1967, FUNDAMENTALS GAS SUR, P346, DOI [DOI 10.1016/B978-1-4832-2901-0.50026-3, 10.1016/B978-1-4832-2901-0.50026-3]