Structural study of extractable lignins from oak heartwood

被引:1
|
作者
Vivas, N
de Gaulejac, NSC
Bourgeois, G
Vitry, C
Pianet, I
Barbe, B
Glories, Y
机构
[1] Univ Victor Segalen, Fac Oenol, F-33405 Talence, France
[2] Univ Bordeaux 1, CESAMO, F-33405 Talence, France
关键词
Quercus; heartwood; lignins; NMR; structure;
D O I
10.1051/jcp:1998156
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
In this work, authors present a structural investigation of two extractible heartwood lignins from Q. robur: LE, extractable by acidic hydroalcoholic medium (MW 23 kDa) and LD, extractable by acidified dioxan (MW 45 kDa), NMR spectrum analysis with 2D TOCSY and HMQC experiments performed the structural characteristics of this two lignins fractions. LD and LE contain principaly monomethoxyl (Gaiacyls) and dimethoxyl (Syringyls) phenolic units with beta-O-4 ary-ether linkage. LD are richer in G units than LE.
引用
收藏
页码:430 / 436
页数:7
相关论文
共 50 条
  • [31] Functional Composition and Structural Features of Higher Plant Lignins
    Sypalova, Yuliya A.
    Shestakov, Semen L.
    Kozhevnikov, Aleksander Yu.
    LESNOY ZHURNAL-FORESTRY JOURNAL, 2023, (05) : 164 - 183
  • [32] Chemical-structural characterization of solvent and thermal extractable material from perhydrous vitrinites
    Iglesias, MJ
    del Río, JC
    Laggoun-Défarge, F
    Cuesta, MJ
    Suárez-Ruiz, I
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2003, 68-9 : 387 - 407
  • [33] Structural Elucidation of Sorghum Lignins from an Integrated Biorefinery Process Based on Hydrothermal and Alkaline Treatments
    Sun, Shao-Long
    Wen, Jia-Long
    Ma, Ming-Guo
    Sun, Run-Gang
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2014, 62 (32) : 8120 - 8128
  • [34] Isolation and structural characterization of the water-extractable polysaccharides from Cassia obtusifolia seeds
    Shang, Mingsheng
    Zhang, Xiaoman
    Dong, Qun
    Yao, Jian
    Liu, Qin
    Ding, Kan
    CARBOHYDRATE POLYMERS, 2012, 90 (02) : 827 - 832
  • [35] Structural characterization of lignins from hydroxycinnamoyl transferase (HCT) down-regulated transgenic poplars
    Peng, Xiao-Peng
    Sun, Shao-Long
    Wen, Jia-Long
    Yin, Wei-Lun
    Sun, Run-Cang
    FUEL, 2014, 134 : 485 - 492
  • [36] Advances in the Study of Heartwood Formation in Trees
    Yang, Shuqi
    Qin, Fangcuo
    Wang, Shengkun
    Li, Xiang
    Zhou, Yunqing
    Meng, Sen
    LIFE-BASEL, 2025, 15 (01):
  • [37] Isolation, Study and Application of Organosolv Lignins
    Kuznetsov, Boris N.
    Malyar, Yuriy N.
    Kuznetsova, Svetlana A.
    Grishechko, Lyudmila I.
    Kazachenko, Alexander S.
    Levdansky, Alexander V.
    Pestunov, Andrey V.
    Boyandin, Anatoly N.
    Celzard, Alan
    JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY, 2016, 9 (04): : 454 - 482
  • [38] HPTLC Investigation of a Ring-Like Discoloration of Pedunculate Oak (Quercus robur L.) Heartwood
    Hofmann, Tamas
    Albert, Levente
    Retfalvi, Tamas
    Feher, Sandor
    JPC-JOURNAL OF PLANAR CHROMATOGRAPHY-MODERN TLC, 2010, 23 (05) : 315 - 319
  • [39] HPTLC Investigation of a Ring-Like Discoloration of Pedunculate Oak (Quercus robur L.) Heartwood
    Tamás Hofmann
    Levente Albert
    Tamás Rétfalvi
    Sándor Fehér
    JPC – Journal of Planar Chromatography – Modern TLC, 2010, 23 : 315 - 319
  • [40] A stilbene from the heartwood of Maclura pomifera
    Djapic, N
    Djarmati, Z
    Filip, S
    Jankov, RM
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2003, 68 (03) : 235 - 237