Optimisation of ICPMS collision/reaction cell conditions for the simultaneous removal of argon based interferences of arsenic and selenium in water samples

被引：40

作者：

Darrouzes, Jerome ^{[1
]}

Bueno, Maite ^{[1
]}

Lespes, Gaetane ^{[1
]}

Holeman, Michel ^{[1
]}

Potin-Gautier, Martine ^{[1
]}

机构：

[1] Univ Pau & Pays Adour, Lab Chim Analyt Bioinorgan & Environm, UMR 5034, F-64000 Pau, France

来源：

TALANTA | 2007年 / 71卷 / 05期

关键词：

ICPMS; selenium; arsenic; speciation; collision cell; reaction cell; water; octopole;

D O I：

10.1016/j.talanta.2006.09.019

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The optimisation of ICPMS collision/reaction cell conditions for the simultaneous analysis of arsenic and selenium is described. A mixture of 3.8 mL min(-1) of H-2 and 0.5 mL min(-1) of He was found to be suitable for the removal of both ArAr+ and ArCl+ interferences. Detection limits down to 30ng (element) L-1 in total analysis, and between 81 and 230ng (element) L-1 in speciation analysis were achieved in chloride matrix (I g L-1 NaCl). After validation, the method was applied to commercially available mineral waters. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：2080 / 2084

页数：5

共 29 条

[1] Optimization of the hyphenation between capillary zone electrophoresis and inductively coupled plasma mass spectrometry for the measurement of As-, Sb-, Se- and Te-species, applicable to soil extracts [J].

Casiot, C ;

Donard, OFX ;

Potin-Gautier, M .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2002, 57 (01) :173-187

[2]

CASIOT C, 1999, SPECTRA ANAL, V206, P17

[3] Analysis of Ling Zhi (Ganoderma lucidum) using dynamic reaction cell ICP-MS and ICP-AES [J].

Chan, YY ;

Lo, SCL .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2003, 18 (02) :146-150

[4] Operational optimisation of ICP -: octopole collision/reaction cell -: MS for applications to ultratrace selenium total and speciation determination [J].

Darrouzès, J ;

Bueno, M ;

Lespès, G ;

Potin-Gautier, M .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2005, 20 (02) :88-94

[5] The effect of ion energy on reactivity and species selectivity in hexapole collision/reaction cell ICP-MS [J].

Dexter, MA ;

Reid, HJ ;

Sharp, BL .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2002, 17 (07) :676-681

[6]

Goupy J, 1999, PLANS EXPERIENCE SUR

[7] Multielemental speciation of As, Se, Sb and Te by HPLC-ICP-MS [J].

Guerin, T ;

Astruc, M ;

Batel, A ;

Borsier, M .

TALANTA, 1997, 44 (12) :2201-2208

[8] Development of analytical systems for the simultaneous determination of the speciation of arsenic [As(III), methylarsonic acid, dimethylarsinic acid, As(V)] and selenium [Se(IV), Se(VI)] [J].

Ipolyi, I ;

Fodor, P .

ANALYTICA CHIMICA ACTA, 2000, 413 (1-2) :13-23

[9] CARBON-ENHANCED INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRIC DETECTION OF ARSENIC AND SELENIUM AND ITS APPLICATION TO ARSENIC SPECIATION [J].

LARSEN, EH ;

STURUP, S .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1994, 9 (10) :1099-1105

[10] Analysis of diluted sea-water at the ng L-1 level using an ICP-MS with an octopole reaction cell [J].

Leonhard, P ;

Pepelnik, R ;

Prange, A ;

Yamada, N ;

Yamada, T .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2002, 17 (03) :189-196

← 1 2 3 →