Synthesis and ROMP of Benzothiadiazole Paracyclophane-1,9-Dienes to Donor-Acceptor Alternating Arylenevinylene Copolymers

被引：12
|
作者：
Komanduri, Venukrishnan [1 ]
Tate, Daniel J. [1 ]
Marcial-Hernandez, Raymundo [1 ]
Kumar, Dharam R. [1 ]
Turner, Michael L. [1 ]
机构：
[1] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England
来源：
MACROMOLECULES | 2019年 / 52卷 / 18期
基金：
英国工程与自然科学研究理事会;
关键词：
RING-OPENING METATHESIS; CONJUGATED POLYMERS; BLOCK-COPOLYMERS; POLYMERIZATION; PHENYLENEVINYLENE; PERFORMANCE;
D O I：
10.1021/acs.macromol.9b01244
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Dialkoxy- and dialkyl-substituted phenylene benzothiadiazole paracyclophane-1,9-diene monomers undergo living ring-opening metathesis polymerization using ruthenium carbene initiators (G3) to give regularly alternating cis,trans-poly(p-phenylenevinylene) benzothiadiazole copolymers. These polymers can be readily isomerized in dilute solution using visible light to the all-trans polymers. The influence of the polymer microstructure and the phenylene substituents on the optical and electrochemical properties of these polymers is examined.
引用
收藏
页码：7137 / 7144
页数：8
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