Air-stable P-chiral bidentate phosphine ligand with (1-adamantyl)methylphosphino group

被引：27

作者：

Imamoto, Tsuneo ^{[1
]}

Kumada, Atsushi ^{[1
]}

Yoshida, Kazuhiro ^{[1
]}

机构：

[1] Chiba Univ, Fac Sci, Dept Chem, Inage Ku, Chiba 2638522, Japan

来源：

CHEMISTRY LETTERS | 2007年 / 36卷 / 04期

关键词：

D O I：

10.1246/cl.2007.500

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Air-stable diphosphine ligand, (R,R)-2,3-bis((1-adamamyl)methylphosphino)quinoxaline, was prepared by the reaction of enantiomerically pure (S)-(1-adamantyl)methylphosphine-borane with 2,3-dichloroquinoxaline. The ligand exhibited excellent enantioselectivities in Rh-catalyzed asymmetric hydrogenation and Pd-catalyzed asymmetric ring-opening reaction.

引用

页码：500 / 501

页数：2

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