Air-stable P-chiral bidentate phosphine ligand with (1-adamantyl)methylphosphino group

被引：27
|
作者：
Imamoto, Tsuneo [1 ]
Kumada, Atsushi [1 ]
Yoshida, Kazuhiro [1 ]
机构：
[1] Chiba Univ, Fac Sci, Dept Chem, Inage Ku, Chiba 2638522, Japan
来源：
CHEMISTRY LETTERS | 2007年 / 36卷 / 04期
关键词：
D O I：
10.1246/cl.2007.500
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Air-stable diphosphine ligand, (R,R)-2,3-bis((1-adamamyl)methylphosphino)quinoxaline, was prepared by the reaction of enantiomerically pure (S)-(1-adamantyl)methylphosphine-borane with 2,3-dichloroquinoxaline. The ligand exhibited excellent enantioselectivities in Rh-catalyzed asymmetric hydrogenation and Pd-catalyzed asymmetric ring-opening reaction.
引用
收藏
页码：500 / 501
页数：2
相关论文
共 50 条
  • [31] Enantioselective synthesis of P-chiral tertiary phosphine oxides with an ethynyl group via Cu(i)-catalyzed azide-alkyne cycloaddition
    Zhu, Ren-Yi
    Chen, Long
    Hu, Xiao-Si
    Zhou, Feng
    Zhou, Jian
    CHEMICAL SCIENCE, 2020, 11 (01) : 97 - 106
  • [32] Air-stable phosphine sulfide ligand precursors for nickel-catalyzed cross-coupling reactions of unactivated aryl chlorides with aryl grignard reagents
    Li, GY
    Marshall, WJ
    ORGANOMETALLICS, 2002, 21 (04) : 590 - 591
  • [33] P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation
    Moeller, Tobias
    Wonneberger, Peter
    Sarosi, Menyhart B.
    Coburger, Peter
    Hey-Hawkins, Evamarie
    DALTON TRANSACTIONS, 2016, 45 (05) : 1904 - 1917
  • [34] Preparation and application of air-stable P,N-bidentate ligands for the selective synthesis of δ-lactone via the palladium-catalyzed telomerization of 1,3-butadiene with carbon dioxide
    Dai, Yao
    Feng, Xiujuan
    Wang, Bin
    He, Ren
    Bao, Ming
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 696 (26) : 4309 - 4314
  • [35] RADIOSYNTHESIS, CEREBRAL DISTRIBUTION, AND BINDING OF [I-125] 1-(P-IODOPHENYL)-3-(1-ADAMANTYL)GUANIDINE, A LIGAND FOR SIGMA-BINDING SITES
    KIMES, AS
    WILSON, AA
    SCHEFFEL, U
    CAMPBELL, BG
    LONDON, ED
    JOURNAL OF MEDICINAL CHEMISTRY, 1992, 35 (25) : 4683 - 4689
  • [36] Asymmetric synthesis of a (P-chiral) As-P bidentate ligand via an organopalladium complex promoted asymmetric Diels-Alder reaction between Ph(2)AsCH=CH2 and 1-phenyl-3,4-dimethylphosphole
    Aw, BH
    Leung, PH
    White, AJP
    Williams, DJ
    ORGANOMETALLICS, 1996, 15 (17) : 3640 - 3643
  • [37] Phosphine free synthesis of copper telluride nanocrystals in 1D and 2D shapes using Dipehylditelluride (DPDTe) as an air-stable source
    Mishra, Mohini
    Patil, Niraj Nitish
    Zubair, Maria
    Kapuria, Nilotpal
    Lebedev, Vasily
    Adegoke, Temilade Esther
    Ryan, Kevin M.
    Singh, Shalini
    NANOTECHNOLOGY, 2022, 33 (30)
  • [38] An alkyl-palladium(II) complex with a bidentate phosphine ligand:: [1,3-bis(diphenylphosphino)propane-P,P′]dimethylpalladium(II) toluene hemisolvate
    Abu-Surrah, AS
    Debaerdemaeker, T
    Huhn, W
    Rieger, B
    Klinga, M
    Repo, T
    Leskelä, M
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : E42 - E43
  • [39] 31P{1H}NMR and carbonyl force constants of unsymmetrical bidentate phosphine complexes of group (VI) metal carbonyls
    Raj, Joe Gerald Jesu
    Pathak, Devendra Deo
    Kapoor, Pramesh N.
    JOURNAL OF MOLECULAR STRUCTURE, 2015, 1087 : 41 - 45
  • [40] Asymmetric synthesis of a (P-chiral) As-P bidentate ligand via an organo-palladium complex promoted asymmetric Diels-Alder reaction between Ph2-AsCH=CH2 and 1-Phenyl-3,4-dimethylphosphole
    Organometallics, 17 (3640):
12345