Electronic spectra and structure of methyl derivatives of 4-nitropyridine N-oxide

被引：0

作者：

Wasylina, L ^{[1
]}

Puszko, A ^{[1
]}

机构：

[1] Univ Econ, Dept Organ Chem, PL-53342 Wroclaw, Poland

来源：

KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII | 2000年 / 06期

关键词：

methyl-4-nitropyridine n-oxides; UV spectra; INDO calculations;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The UV spectra of seven methyl derivatives of 4-nitropyridine N-oxide in ethanol have been examined. The electronic spectra were calculated by a modified INDO method. Transition energies, intensities and assignments were compared with UV spectra. Spectroscopic manifestations of intramolecular interaction indicate that methyl groups modify the electronic interaction between the N-oxide and NO2 groups mainly through a steric strain.

引用

页码：786 / 793

页数：8

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