Photochemistry and reaction intermediates of the bimetallic Group VIII cyclopentadienyl metal carbonyl compounds, (η5-C5H5)2M2(CO)4 and their derivatives

被引：81

作者：

Bitterwolf, TE ^{[1
]}

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷

关键词：

photochemistry; reaction intermediates; group VIII; cyclopentadienyl metal carbonyl compounds;

D O I：

10.1016/S0010-8545(00)00251-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bonding, structures and photochemistry of the Group VIII metal cyclopentadienyl carbonyl derivatives of the form, (eta(5)-C5H5)(2)M-2(CO)(4), where M = Fe, Ru and Os, are reviewed. The primary emphasis of the review is to bring together the somewhat complex literature in this field, to critically examine the evidence and interpretations and to identify areas for future research opportunities. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：419 / 450

页数：32

共 139 条

[1] PREPARATION AND PHOTOCHEMISTRY OF METAL-METAL BONDED HETERODINUCLEAR PRECURSORS TO TETRACARBONYLCOBALT(O), TRICARBONYL ETA-5-CYCLOPENTADIENYL) MOLYBDENUM(I), TRICARBONYL, "ETA-5-CYCLOPENTADIENYL)TUNGSTEN(I), AND DICARBONYL ETA-5-CYCLOPENTADIENYL(IRON(I)
ABRAHAMSON, HB
WRIGHTON, MS
[J]. INORGANIC CHEMISTRY, 1978, 17 (04) : 1003 - 1008
[2] PHOTOCHEMISTRY AND ELECTRONIC-STRUCTURE OF BIS(DICARBONYL(ETA-5-CYCLOPENTADIENYL)RUTHENIUM) AND ITS IRON ANALOG
ABRAHAMSON, HB
PALAZZOTTO, MC
REICHEL, CL
WRIGHTON, MS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (15) : 4123 - 4127
[3] STEREOCHEMICAL CONTROL OF ALKYNE OLIGOMERIZATION AT A DIRUTHENIUM CENTER - X-RAY STRUCTURES OF [RU2(CO)(MU-CO)(MU-C4H4CME2)(ETA-C5H5)2] AND [RU2(MU-CO)[MU-C4(CO2ME)4CH2](ETA-C5H5)2]
ADAMS, PQ
DAVIES, DL
DYKE, AF
KNOX, SAR
MEAD, KA
WOODWARD, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (05) : 222 - 224
[4] HYDRIDE REDUCTION OF [(ETA-5-INDENYL)FE(CO)3]BF4 - EVIDENCE FOR (ETA-5-INDENYL)(CO)2FECHO AND (ETA-5-INDENYL)(CO)2FEH
AHMED, H
BROWN, DA
FITZPATRICK, NJ
GLASS, WK
[J]. INORGANICA CHIMICA ACTA, 1989, 164 (01) : 5 - 6
[5] HYDRIDE ADDITION TO [(ETA-5-INDENYL)FE(CO)3]BF4 - EVIDENCE FOR ETA-3-INDENYL INTERMEDIATES
AHMED, H
BROWN, DA
FITZPATRICK, NJ
GLASS, WK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 418 (01) : C14 - C16
[6] EVOLUTION OF THE TRANSIENT VIBRATIONAL-SPECTRUM FOLLOWING SHORT-PULSE EXCITATION
ANFINRUD, PA
HAN, C
LIAN, T
HOCHSTRASSER, RM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (03) : 1180 - 1184
[7] FEMTOSECOND INFRARED-SPECTROSCOPY - ULTRAFAST PHOTOCHEMISTRY OF IRON CARBONYLS IN SOLUTION
ANFINRUD, PA
HAN, CH
LIAN, TQ
HOCHSTRASSER, RM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (02) : 574 - 578
[8] An ultrafast time-resolved UV visible absorption study of the UV photochemistry of [(eta(5)-C5H5)Fe(CO)(2)](2)
Arnold, CJ
Ye, TQ
Perutz, RN
Hester, RE
Moore, JN
[J]. CHEMICAL PHYSICS LETTERS, 1996, 248 (5-6) : 464 - 469
[9] MOLECULAR-ORBITAL ANALYSIS OF THE METAL-METAL INTERACTION IN SOME CARBONYL-BRIDGED BINUCLEAR COMPLEXES
BENARD, M
[J]. INORGANIC CHEMISTRY, 1979, 18 (10) : 2782 - 2785
[10] Ligand exchange photochemistry of M2(CO)4(μ-η5,η5-C5H4CH2C5H4) (M = Fe or Ru) and thermal acetylene exchange of Ru2(CO)(μ-CO)[μ-η1:η1-(C6H5)2C2](μ-η5,η5-C5H4CH2C5H4) -: The molecular structures of Ru2(CO)(σ-C6H5)(μ-CO)[μ-P(C6H5)2](μ-η5,η5-C5H4CH2C5H4) and Ru2(CO)(μ-CO)[μ-η1,η3-C6H5C=C(C6H5)O]-(μ-η5,η5-C5H4CH2C5H4)
Bitterwolf, TE
Haener, JL
Shade, JE
Rheingold, AL
Yap, GPA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 547 (01) : 23 - 33

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